Darstellung von α-aminophosphonsäureestern und verwandten Verbindungen

6533b830fe1ef96bd1296ef5

RESEARCH PRODUCT

Darstellung von α-aminophosphonsäureestern und verwandten Verbindungen

subject

Chemistry General Chemistry Medicinal chemistry

description

Aus N-Fluorsulfonylaldiminen und Phosphorigsauredialkylestern werden N-Fluorsulfonyl-α-amino-phosphonsaureester erhalten. Durch saure Verseifung konnen hieraus je nach den Bedingungen α-Aminophosphonsauren oder deren Ester gewonnen werden. Durch Anlagerung sekundarer Phosphinoxide sekundarer Phosphine oder tertiarer Phosphinhydrohalogenide an N-Fluorsulfonylaldimine entstehen in α-Stellung durch die N-Fluorsulfonylamido-Gruppe substituierte tertiare Phosphinoxide, tertiare Phosphine oder Phosphoniumsalze.

year	journal	country	edition	language
1968-01-01	Monatshefte für Chemie - Chemical Monthly

https://doi.org/10.1007/bf00908943

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