6533b831fe1ef96bd12998c9
RESEARCH PRODUCT
Self-assembly of programmed building blocks into structurally uniform dendrimers.
Yuliya RudzevichChulsoon MoonValentyn RudzevichVolker BöhmerIngo SchnellKarl Fischersubject
Models MolecularMagnetic Resonance SpectroscopyStereochemistryChemistryOrganic solventMolecular ConformationHydrogen BondingGeneral ChemistryBiochemistrySolution structureCatalysisMolecular aggregationCrystallographyColloid and Surface ChemistryDynamic light scatteringPhenolsDendrimerCalixareneUreaSelf-assemblyCalixarenesdescription
Selective and independent dimerization of tri- and tetraurea derivatives was used to build up dendritic assemblies which are uniform in size and structure. Dendrimers with the total molecular masses of about 25 000 g/mol were obtained. The existence of uniform assemblies was proved by 1H and 1H DOSY NMR experiments and also by dynamic light scattering.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-09-23 | Journal of the American Chemical Society |