6533b832fe1ef96bd129a1af

RESEARCH PRODUCT

Crystal structure of t-Butylcalix[8]arene octamethyl ether

Volker BöhmerMichael BolteVasiliy V. Brusko

subject

ChloroformChemistryOrganic ChemistryEtherGeneral ChemistryCrystal structureTriclinic crystal systemInorganic Chemistrychemistry.chemical_compoundCrystallographyLattice (order)CalixareneMaterials ChemistryMolecule

description

Abstract The title compound 1a crystallized with a molecule of chloroform in a triclinic lattice, space group P-1, with a=16.5215(19) A, b=17.4181(19) A, c=18.7403(18) A, α=78.328(8)°, β=64.210(8)°, γ=87.863(9)°, Z=2. The molecule assumes a not yet observed conformation with approximate (not crystallographic) C4V-symmetry with the inclusion of one molecule of chloroform in the molecular cavity. Layers of molecules are packed in alternating order in the crystal lattice.

yearjournalcountryeditionlanguage
2002-01-01Journal of Supramolecular Chemistry
https://doi.org/10.1016/s1472-7862(02)00079-5