6533b832fe1ef96bd129b0c3
RESEARCH PRODUCT
The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6
Jas S. Wardsubject
jodivetysidoksetkemiaiodinesolid-state chemistrykiinteän olomuodon kemiadescription
The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield. peerReviewed
year | journal | country | edition | language |
---|---|---|---|---|
2022-01-01 |