6533b832fe1ef96bd129b0c3

RESEARCH PRODUCT

The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6

Jas S. Ward

subject

jodivetysidoksetkemiaiodinesolid-state chemistrykiinteän olomuodon kemia

description

The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-202301031052