6533b833fe1ef96bd129ca8e
RESEARCH PRODUCT
Glycoside synthesis via electrophile-induced activation of N-allyl carbamates
Jörg ZimmerHorst Kunzsubject
chemistry.chemical_classificationDipeptideorganic chemicalsOrganic ChemistryDisaccharideGlycosideBiochemistryMedicinal chemistrychemistry.chemical_compoundchemistryAldoseDrug DiscoveryElectrophileMonosaccharidelipids (amino acids peptides and proteins)GlycosylStereoselectivitydescription
Abstract O-Benzyl-, O-acyl-, N-acyl- and isopropylidene-protected glycosyl N-allylcarbamates, obtained from anomerically unprotected monosaccharides and allyl isocyanate, are activated by an electrophile-induced cyclisation and react with hydroxyl compounds to form the corresponding glycosides.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-04-01 | Tetrahedron Letters |