6533b835fe1ef96bd12a0133
RESEARCH PRODUCT
Synthesis of quadruped-shaped polyfunctionalized o-carborane synthons
Alberto V. PugaClara ViñasFrancesc TeixidorReijo SillanpääRaikko Kivekässubject
DendrimersIcosahedral CarboranesStereochemistryMolecular ConformationNeutron-Capture TherapySupramolecular Assemblieschemistry.chemical_elementBoranesCrystallography X-Ray010402 general chemistry01 natural sciencesCatalysisMolecular conformationDendrimerQUIMICA ANALITICAMaterials ChemistryCluster (physics)BoranesBoronta116CancerIodination010405 organic chemistryChemistryPolysubstituted FrameworksSynthonMetals and AlloysHalogenationGeneral Chemistry3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsC-HChemistryCrystallographyCeramics and CompositesCarboraneDerivativesIodinedescription
[EN] o-Carborane derivatives with precisely defined patterns of substitution have been prepared from 8,9,10,12-I-4-1,2-closo-C2B10H8 by replacing the iodine atoms, bonded to four adjacent boron vertices in the cluster, with allyl, and subsequently 3-hydroxypropyl groups. The resulting structures, comprising four pendant arms and two reactive vertices located on opposite sides of a central o-carborane core, can be envisaged as versatile precursors for dendritic growth
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-01-25 | Chemical Communications |