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RESEARCH PRODUCT
Efficient energy transfer in a tri-chromophoric dyad containing BODIPYs and corrole based on a truxene platform
Xuemei YuanShi-fa WangTing MengJian YangClaude P. GrosHaijun XuGuo-xiang XinFangjian Caisubject
chemistry.chemical_compound010405 organic chemistryChemistryEnergy transferMoleculeGeneral ChemistryCorroleBODIPY010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesEfficient energy usedescription
A star-shaped molecule was designed and synthesized based on a known central truxene platform. Two BODIPY derivatives and one corrole macrocycle were introduced and connected to the 2, 7 and 12-positions of the truxene unit by Suzuki coupling. The dyad was fully characterized by UV-vis absorption, proton nuclear magnetic resonance, mass spectrometry. The direction of energy transfer upon electronic excitation was explored, and the star-shaped molecule system exhibits a highly efficient photoinduced energy transfer process from the excited BODIPY part to the corrole unit.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-08-21 | Journal of Porphyrins and Phthalocyanines |