Studien Zum Ablauf Der Substitution XIII. Zur Existenz Von Durchgangsradikalen Bei Der Umsetzung Von Dibenzoylperoxyd Mit Aliphatisch-Aromatisch Substituierten Sek. Aminen

6533b837fe1ef96bd12a25e8

RESEARCH PRODUCT

Studien Zum Ablauf Der Substitution XIII. Zur Existenz Von Durchgangsradikalen Bei Der Umsetzung Von Dibenzoylperoxyd Mit Aliphatisch-Aromatisch Substituierten Sek. Aminen

subject

Chemistry Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry

description

Die Darstellung von O-Benzoyl- und O-Acetyl-N-athyl-N-phenyl-hydroxylamin (I bzw. II) wird beschrieben. I entsteht auch bei der Einwirkung von Dibenzoylperoxyd auf N-Athylanilin. Es wird bewiesen, das die Kernsubstitution in o- und p-Stellung nicht uber I lauft, sondern uber Durchgangsradikale erfolgt.

year	journal	country	edition	language
1957-07-10	Justus Liebigs Annalen der Chemie

https://doi.org/10.1002/jlac.19576060104

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