6533b837fe1ef96bd12a27d9
RESEARCH PRODUCT
Catalytic activity of a CuGHK peptide-based porous material
Carlos Marti-gastaldoNuria MartínNeyvis Almora-barriosFrancisco G. Cirujanosubject
Benzaldehydechemistry.chemical_classificationchemistry.chemical_compoundNitroaldol reactionchemistryNitromethaneLysineSide chainMoleculePeptideCombinatorial chemistryCatalysisCatalysisdescription
The CuGHK peptide-based porous material with a periodic distribution of pockets decorated with lysine side chain active sites was synthesized using a room temperature one-step method and used as a heterogeneous organocatalyst. The pockets are capable of benzaldehyde molecule uptake and show high activity in the Henry reaction with nitromethane. Mechanistic pathways are investigated using an integrative experimental/computational approach.
year | journal | country | edition | language |
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2021-08-09 | Catalysis Science & Technology |