6533b837fe1ef96bd12a3046

RESEARCH PRODUCT

Formation of supramolecular aggregates by hydrogen bonding based on bispyrimidine and bisbarbituric acid

Steffen DenzingerLiyan WangZhiqiang WangHelmut RingsdorfJiacong ShenXi Zhang

subject

Aggregate (composite)Polymers and PlasticsHydrogen bondChemistryOrganic Chemistrytechnology industry and agricultureSupramolecular chemistryCondensed Matter PhysicsHydrolysisChemical engineeringMolar ratioPolymer chemistryMaterials ChemistryOrganic chemistryChemical solutionMoleculePhysical and Theoretical Chemistry

description

Hydrogen bonds between bispyrimidine and bisbarbituric acid in equal molar ratio can lead to the formation of supramolecular aggregates. This is established by TEM, IR and DSC measurements. Additionally, WAXS pattern showed that the aggregate is of laminar structure. Both the hydrolysis of this system and termination of the aggregate's growth were studied.

https://doi.org/10.1002/macp.1997.021980229