6533b839fe1ef96bd12a5cbd
RESEARCH PRODUCT
A Novel Zeolite-Induced Population of a Planar Viologen Conformation. New Viologen Charge Transfer Complexes and Alkene/Viologen/Zeolite Arrays
Edward L. ClennanAnd Frank JensenAndrea PaceJamie Singletonsubject
chemistry.chemical_classificationeducation.field_of_studyConformational changeChemistryAlkenePopulationViologenCharge (physics)Settore CHIM/06 - Chimica OrganicaPhotochemistrySurfaces Coatings and FilmsPlanarMaterials ChemistrymedicinePhysical and Theoretical ChemistryeducationZeolitemedicine.drugZeolites Binding constants Electrochromic display devices Oxygenationdescription
A rare example of a novel zeolite-induced conformational change and a mechanism for this process are suggested in order to rationalize an unexpected spontaneous intrazeolite reduction observed during preparation of a new viologen (MQ2+)-doped zeolite (NaY). In addition, the formations of six new alkene/viologen/ zeolite charge transfer (CT) arrays using NaMQY and the previously reported NaMVY are also reported. The binding constants between MQ2+ and MV2+ and 2,3-dimethyl-2-butene (TME) were determined using the Benesi-Hildebrand approach, and the stabilities of these CT complexes are compared to their intrazeolite analogue.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-03-19 |