6533b851fe1ef96bd12a8ce6
RESEARCH PRODUCT
false
G. MeyerhoffKlaus Weißkopfsubject
Arrhenius equationsymbols.namesakechemistry.chemical_compoundCondensation polymerReaction rate constantAminolysisMonomerChemistryDimethyl sulfoxideHexylamineKineticsPolymer chemistrysymbolsdescription
The aminolysis of diphenyl terephthalate by means of hexylamine was studied in dimethyl sulfoxide as a model reaction for polyamidation. The kinetic analysis showed that the two ester groups of the diphenyl ester do not react independently. Furthermore, the reaction of the first ester group was of mixed second and third order, while the reaction of the second ester group contained only a second order term. The rate constants found were used to determine the Arrhenius activation parameters.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1986-02-01 | Die Makromolekulare Chemie |