6533b851fe1ef96bd12a8e62
RESEARCH PRODUCT
A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC≈ 68 K
Paul T. WoodAntonio AlberolaCarlos J. Gómez GarcíaSimon M. Humphreysubject
Inorganic chemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryChlorideOxygenCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSodium saltchemistry.chemical_compoundchemistryPyridinePolymer chemistryMaterials ChemistryCeramics and CompositesmedicineAntiferromagnetismCarboxylatemedicine.drugdescription
Reaction of Co(II) chloride with the sodium salt of 2-mercaptonicotinic acid in water at 200 degrees C results in the formation of Co4(2-mna)4(H2O), which orders as a canted antiferromagnet at 68 K.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-04-04 | Chemical Communications |