Zur Kenntnis der o ‐Chinone, XVI. Additionsreaktionen mit 3‐Methoxy‐ o ‐chinon

6533b851fe1ef96bd12aa071

RESEARCH PRODUCT

Zur Kenntnis der o ‐Chinone, XVI. Additionsreaktionen mit 3‐Methoxy‐ o ‐chinon

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

HCl-Addition an 3-Methoxy-o-chinon und nachfolgende Entmethylierung liefert 5-Chlor-pyrogallol, Benzolsulfinsaure-Addition und anschliesende Methylierung fuhrt zum 2.3.4-Trimethoxy-diphenylsulfon. Thiophenol wird in 6-Stellung eingelagert.–An das (nicht fasbare) Intermediarprodukt der Purpurogallinbildung aus Pyrogallol, das 3-Hydroxy-o-chinon, wird Benzoisulfinsaure zu 3.4.5-Trihydroxy-diphenylsulfon addiert; dessen Permethylierungsprodukt wie auch das 2.3.4-Trimethoxy-Isomere werden zum Konstitutionsbeweis auf unabhangigen Wegen synthetisiert.

year	journal	country	edition	language
1961-05-01	Chemische Berichte

https://doi.org/10.1002/cber.19610940516

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