6533b853fe1ef96bd12aca51
RESEARCH PRODUCT
Die Cooligomerisierung von butadien mit α-hydroxycarbonsäureestern
Reinhold KlüterHellmut SingerMargot Berndsubject
inorganic chemicalsOrganic Chemistrychemistry.chemical_elementEtherEthyl esterBiochemistryLactic acidCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryPolymer chemistryMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryTriphenylphosphineGlycolic acidPalladiumdescription
Abstract Glycolic acid butyl ester as well as lactic acid ethyl ester react with butadiene in the presence of palladium(II) acetylacetonate and triphenylphosphine as catalyst. The main product is the 2-trans, 7-octadienyl ether of the hydroxy acid ester, which is formed in yields from 65 to 80% at room temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1977-09-01 | Journal of Organometallic Chemistry |