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RESEARCH PRODUCT

Study of the annealing conditions and photoelectrochemical characterization of a new iron oxide bi-layered nanostructure for water splitting

José García-antónRita Sánchez TovarR.m. Fernández-domeneB. Lucas-granados

subject

Electron mobilityNanostructureMaterials scienceAnnealing (metallurgy)HematiteNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesINGENIERIA QUIMICAAnnealingsymbols.namesakeWater splittingPhotocurrentNanoestructuresRenewable Energy Sustainability and the EnvironmentAnodizingPhotocatalyst021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDielectric spectroscopyElectroquímicaChemical engineeringsymbolsWater splittingAnodization0210 nano-technologyRaman spectroscopy

description

Iron oxide nanostructures have emerged as promising materials for being used as photocatalysts for hydrogen production due to their advantageous properties. However, their low carrier mobility and short hole diffusion length limit their efficiency in water splitting. To overcome these drawbacks, in the present study, we synthetized a new hematite (alpha-Fe2O3) bi-layered nanostructure consisting of a top nanosphere layer and a nanotubular underneath one by electrochemical anodization. Annealing parameters such as temperature, heating rate and atmosphere were studied in detail in order to determine the optimum annealing conditions for the synthetized nanostructure. The obtained new bi-layered nanostructure was characterized by Field Emission Scanning Electron Microscopy, Raman Spectroscopy, Mott-Schottky analysis and Electrochemical Impedance Spectroscopy. The results show the best water splitting performance for the bi-layered nanostructure annealed in argon atmosphere at 500 degrees C at a heating rate of 15 degrees C min(-1) achieving a photocurrent density of similar to 0.143 mA cm(-2) at 1.54 V (vs. RHE). The results indicate that the bi-layered nanostructure is an efficient photocatalyst for applications such as water splitting

yearjournalcountryeditionlanguage
2016-08-01
10.1016/j.solmat.2016.04.005https://doi.org/10.1016/j.solmat.2016.04.005