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RESEARCH PRODUCT
Alkylated Aromatic Thioethers with Aggregation‐Induced Emission Properties—Assembly and Photophysics
Kateryna SoloviovaCristian A. StrassertMichael GieseChristoph WölperAndrea SowaSteffen RiebeJacqueline StelzerMarco SacconeJens Voskuhlsubject
aggregation-induced emissionPhotoluminescenceChemiemesomorphismCrystal structure010402 general chemistryPhotochemistry01 natural sciencesBiochemistrylaw.inventionDifferential scanning calorimetryOptical microscopelawX-ray diffractometric analysis010405 organic chemistryChemistryOrganic Chemistryself-assemblyGeneral ChemistryFluorescence0104 chemical sciencesTransmission electron microscopyfluorescenceSettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelf-assemblyAbsorption (chemistry)description
In this contribution, we present the synthesis and self-assembly of alkylated thioethers with interesting photophysical properties. To this end, the emission, absorption and excitation spectra in organic solvents and as aggregates in water were measured as well as the corresponding photoluminescence quantum yields and lifetimes. The aggregates in aqueous media were visualized and measured using transmission electron microscopy. Besides that, crystal structures of selected compounds allowed a detailed discussion of the structure–property relationship. Furthermore, the mesomorphic behavior was investigated using polarized optical microscopy (POM) as well as differential scanning calorimetry (DSC).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-01-01 | Chemistry – An Asian Journal |