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RESEARCH PRODUCT
Organotin(IV) complexes ofN-[(2Z)-3-hydroxy-1-methyl-2-butenylidene]glycine
Eleonora RivarolaCheerfulman MasharingSushmita DuttaUlli EnglertTushar S. Basu Baulsubject
ChemistrySodiumPotassiumHeteroatomchemistry.chemical_elementInfrared spectroscopyHalideGeneral ChemistryMedicinal chemistrychemistry.chemical_compoundGlycineMössbauer spectroscopyOrganic chemistryBenzenedescription
Organotin(IV) derivatives of N-[(2Z)-3-hydroxy-1-methyl-2-butenylidene]glycine have been synthesized and characterized by 1H, 13C, 119Sn NMR, 119Sn Mossbauer, and IR spectroscopy along with elemental analyses. The di- and triorganotin(IV) complexes were readily obtained from the reactions of organotin halides and sodium/potassium N-[(2Z)-3-hydroxy-1-methyl-2-butenylidene]glycinate. The diorganotin compound reacted with Ph3SnCl in refluxing benzene to give the mixed organotin dinuclear complex of composition Ph2Sn(2-OC(CH3)-C(H)C(CH3)NCH2COO)·Ph3SnCl, which was characterized by single crystal X-ray structure determination. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:149–154, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10116
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-01-01 | Heteroatom Chemistry |