6533b854fe1ef96bd12afa48

RESEARCH PRODUCT

The pentafluorophenyl group as π-acceptor for anions: a case study† †This manuscript is dedicated to Prof. Jean-Marie Lehn on the occasion of his 75th birthday. ‡ ‡Electronic supplementary information (ESI) available. CCDC 967089, 967097, 1005267–1005289. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02762k Click here for additional data file. Click here for additional data file.

Michael GieseMarkus AlbrechtArto ValkonenKari Rissanen

subject

Chemistry

description

A unique structural study investigates the variability of anion–π bonding in the solid state structures of pentafluorophenyl arenes. The hapticity concept is used as tool to describe the structural differences of various anion–π complexes.

10.1039/c4sc02762khttp://europepmc.org/articles/PMC5586208