0000000000969453
AUTHOR
Michael Giese
On the blue phase structure of hydrogen-bonded liquid crystals via 19F NMR
Abstract 19 F NMR spectra are simulated for blue phase I of FPHG( St 1.5 ∗ Ap 1.5 ) based on a model of a double-twisted substructure inside cylinders that form a body-centred cubic lattice. A kinetic matrix is included to describe jump processes over quarter pitch lengths. Though the lines in the NMR spectra are broad and featureless, changes in the widths and positions with temperature are well described by the blue phase model structure. The spectra in the chiral nematic N∗ phase are also simulated. Dynamics in the BP I are found to be slower than in the N∗ phase.
Pentafluorophenyl salicylamine receptors in anion–π interaction studies
A crystal structure analysis confirms the appropriateness of pentafluorophenyl salicylamine (1a) as a π-acceptor for anion–π interactions. Crystals of 1a·HCl show that the OH-group fixes the anion in a η2-type binding motif above the electron-deficient arene. Attempts to find some relevance for this weak intermolecular force in solution failed. Stronger CH–, NH– and OH–anion interactions are dominant over the weak anion–π interactions. Due to the hydrogen bonding, the non-fluorinated receptor exhibits the highest binding constants within this series.
Weak Intermolecular Anion–π Interactions in Pentafluorobenzyl-Substituted Ammonium Betaines
A series of ammonium–carboxylate and ammonium–sulfonate betaines was synthesized and studied by single-crystal X-ray diffraction analysis to investigate the weak intermolecular interactions as well as the intramolecular interactions in the solid state. None of the expected intramolecular anion–π interactions could be observed, probably because of the steric demands and the reduced nucleophilicity of the anionic part of the betaines. Nevertheless, a weak intermolecular anion–π interaction between the anionic part of the betaine and the pentafluorophenyl unit is present in the structure of 5a.
The pentafluorophenyl group as π-acceptor for anions: a case study
Chemical science 6(1), 354-359 (2015). doi:10.1039/C4SC02762K
Single-Crystal X-ray Diffraction and Solution Studies of Anion-π Interactions inN-(Pentafluorobenzyl)pyridinium Salts
A solid-state structural study on anion–π interaction in various N-(pentafluorobenzyl)pyridinium salts accompanied by NMR spectroscopic investigations is presented. The crystal structures of 1a–1d reveal different kinds of contacts with anions, including anion–π interactions. In particular, the solid-state structure of 1b-I3 shows distinct evidence of anion–π interactions. Attempts to study anion–π interactions in solution were not successful, but their presence in solution could not be ruled out.
From attraction to repulsion : anion–π interactions between bromide and fluorinated phenyl groups
Anion–π interactions in crystals of fluorobenzyl ammonium salts depend on the degree of fluorination at the aromatics.
Synthesis of 7-Pentafluorophenyl-1H-indole: An Anion Receptor for Anion–π Interactions
7-Pentafluorophenyl-1H-indole has the potential to be a key compound for the investigation of anion–π interactions in solution. Unfortunately, it was not possible to obtain it by aryl–aryl coupling reaction. Finally, it has been prepared by Bartoli indole synthesis. The key compound as well as analogues were submitted to preliminary studies of anion binding. Single crystals of two key receptors were obtained.
Solid state anion–π interactions involving polyhalides
The stabilization of polyhalides in the solid state with the support of electron-deficient pentafluorophenyl groups is described. Furthermore, a synthetic approach towards the sensitive tetraiodide dianion is described and ESI mass spectrometric evidence for its presence in solution is reported.
Mesogens with Aggregation-Induced Emission Formed by Hydrogen Bonding
In this contribution, we report a supramolecular approach toward mesogens showing aggregation-induced emission (AIE). AIE-active aromatic thioethers, acting as hydrogen-bond donors, were combined with alkoxystilbazoles as hydrogen-bond acceptors. Upon self-assembly, hydrogen-bonded complexes with monotropic liquid crystalline behavior were obtained. In addition, it was found that the introduction of a chiral citronellyl side chain leads to drastic bathochromic shift of the emission, which was not observed for linear alkyl chains. The mesomorphic behavior, as well as the photophysical properties as a solid and in the mesophase of the liquid crystalline assemblies, were studied in detail.
Hydrogen-bonded liquid crystals with broad-range blue phases
We report a modular supramolecular approach for the investigation of chirality induction in hydrogen-bonded liquid crystals. An exceptionally broad blue phase with a temperature range of 25 °C was found, which enabled its structural investigation by solid state 19F-NMR studies and allowed us to report order parameters of the blue phase I for the first time.
Di-, Tri-, and Tetra(pentafluorophenyl) Derivatives for Oligotopic Anion−π Interactions
The present study describes a series of pentafluorobenzyl ammonium salts with two, three, or four C6F5 units in order to investigate simultaneous interactions of several perfluorinated arenes with anions in the crystalline state. Most of the structures show multiple anion-π contacts. However, only 6·2HI reveals an effective encapsulation of the iodide ion by the aromatic units. For comparison, the structure of 4b is investigated because it offers two π-systems with inverse charge distribution to a bromide anion. Only the electron-deficient π-system of the pentafluorophenyl group interacts with the anion.
ortho -Fluorination of azophenols increases the mesophase stability of photoresponsive hydrogen-bonded liquid crystals
Photoresponsive liquid crystals (LCs) whose alignment can be controlled with UV-Visible light are appealing for a range of photonic applications. From the perspective of exploring the interplay between the light response and the self-assembly of the molecular components, supramolecular liquid crystals are of particular interest. They allow elaborating the structure-property relationships that govern the optical performance of LC materials by subtle variation of the chemical structures of the building blocks. Herein we present a supramolecular system comprising azophenols and stilbazoles as hydrogen-bond donors and acceptors, respectively, and show that ortho-fluorination of the azophenol dr…
Experimental investigation of anion-π interactions : Applications and biochemical relevance
Chemical communications 52(9), 1778 - 1795(2016). doi:10.1039/C5CC09072E
Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding
A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.
Naturally occurring polyphenols as building blocks for supramolecular liquid crystals – substitution pattern dominates mesomorphism
A modular supramolecular approach towards hydrogen-bonded liquid crystalline assemblies based on naturally occurring polyphenols is reported. The combination of experimental observations, crystallographic studies and semi-empirical analyses of the assemblies provides insight into the structure–property relationships of these materials. Here a direct correlation of the number of donor OH-groups as well as their orientation with the mesomorphic behavior is reported. We discovered that the number and orientation of the OH-groups have a stronger influence on the mesomorphic behavior of the supramolecular assemblies than the connectivity (e.g. stilbenoid or chalconoid) of the hydrogen bond donor…
Anion-π Interactions with Fluoroarenes.
A modular approach towards functional supramolecular aggregates - subtle structural differences inducing liquid crystallinity.
Herein we report an efficient modular approach to supramolecular functional materials. Hierarchical self-assembly of azopyridine derivatives and hydrogen-bond donors yielded discotic assemblies. Subtle differences in the core units introduced mesomorphic behaviour and fast photo-response of the liquid crystals based on phloroglucinol. The presented results prove the benefits of a modular methodology towards highly responsive materials with tailor-made properties.
Photoresponsive Halogen-Bonded Liquid Crystals: The Role of Aromatic Fluorine Substitution
A new strategy for controlling the liquid crystalline and photophysical properties of supramolecular mesogens assembled via halogen bonding is reported. Changing the degree of fluorination at the halogen-bond donor of the supramolecular liquid crystal allows for the fine-tuning of the halogen bond strength and thereby provides control over the temperature range of the mesophase. At least three fluorine atoms have to be present to ensure efficient polarization of the halogen-bond donor and the formation of a mesophase. In addition, it was found that stilbazole acceptors are superior to their azopyridine counterparts in promoting stable liquid crystalline phases. The halogen-bond-driven supra…
On the impact of linking groups in hydrogen-bonded liquid crystals – a case study
The impact of the linking group in hydrogen-bonded liquid crystals is systematically studied by a modular approach. POM and DSC results exhibited tremendous differences in the mesomorphic behaviour of the assemblies, due to the versatile linkages of the side chains, which were correlated with structural features and the elctronical nature of the side chains.
Alkylated Aromatic Thioethers with Aggregation‐Induced Emission Properties—Assembly and Photophysics
In this contribution, we present the synthesis and self-assembly of alkylated thioethers with interesting photophysical properties. To this end, the emission, absorption and excitation spectra in organic solvents and as aggregates in water were measured as well as the corresponding photoluminescence quantum yields and lifetimes. The aggregates in aqueous media were visualized and measured using transmission electron microscopy. Besides that, crystal structures of selected compounds allowed a detailed discussion of the structure–property relationship. Furthermore, the mesomorphic behavior was investigated using polarized optical microscopy (POM) as well as differential scanning calorimetry (…
Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors
A rare anion-π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study.
The pentafluorophenyl group as π-acceptor for anions: a case study† †This manuscript is dedicated to Prof. Jean-Marie Lehn on the occasion of his 75th birthday. ‡ ‡Electronic supplementary information (ESI) available. CCDC 967089, 967097, 1005267–1005289. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02762k Click here for additional data file. Click here for additional data file.
A unique structural study investigates the variability of anion–π bonding in the solid state structures of pentafluorophenyl arenes. The hapticity concept is used as tool to describe the structural differences of various anion–π complexes.
Supramolecular Modification of ABC Triblock Terpolymers in Confinement Assembly
The self-assembly of AB diblock copolymers in three-dimensional (3D) soft confinement of nanoemulsions has recently become an attractive bottom up route to prepare colloids with controlled inner morphologies. In that regard, ABC triblock terpolymers show a more complex morphological behavior and could thus give access to extensive libraries of multicompartment microparticles. However, knowledge about their self-assembly in confinement is very limited thus far. Here, we investigated the confinement assembly of polystyrene-block-poly(4-vinylpyridine)-block-poly(tert-butyl methacrylate) (PS-b-P4VP-b-PT or SVT) triblock terpolymers in nanoemulsion droplets. Depending on the block weight fractio…
Controlling the position of anions relative to a pentafluorophenyl groupw
The position of an anion above an electron-deficient arene can be controlled by the geometry of appended directing groups. Here a series of ammonium substituted pentafluorophenyl derivatives is investigated. The presented results are one step on the way to find the ideal structural features for an effective and superior receptor for anion–π studies.
Alkyloxy modified pyrene fluorophores with tunable photophysical and crystalline properties
Novel alkyloxy modified 2,7-di-tert-butyl-4,5,9,10-tetra(arylethynyl)pyrenes were prepared through a straightforward Sonogashira coupling approach. Optical properties such as quantum yields and absorption/emission spectra of the fluorophores were investigated by UV/Vis and fluorescence measurements. Aggregation induced excimer formation of the chromophores in polar solvents and in the solid state was proved by the presence of a characteristic bathochromically shifted emission band and a decrease of the emission capability. These results strongly indicate the unexpected observation that the excimer formation of adjacent pyrene rings is not prevented by the introduction of bulky tert-butyl su…
Structure-property relationships in aromatic thioethers featuring aggregation-induced emission : Solid-state structures and theoretical analysis
We describe in this paper a structure–property relationship study of aromatic thioethers with aggregation-induced emission (AIE) properties. We combine a structural analysis based on geometrical consideration with an in-depth analysis of the crystalline packing supported by quantum mechanical calculations. Our results allow us to correlate the enhanced fluorescence quantum yields with the significant increase of C–H⋯π and the decrease of π⋯π interactions in the solid state – a result which supports the well-accepted AIE mechanism quantitatively.
Photo-switching and -cyclisation of hydrogen bonded liquid crystals based on resveratrol
A series of hydrogen-bonded liquid crystals based on resveratrol and resveratrone is reported and investigated with respect to their photo-switchability (at 405 nm) and photo-cyclisation (at 300 nm).
Chiral mesophases of hydrogen-bonded liquid crystals
The chiral induction in hydrogen-bonded liquid crystals is investigated. The experimental study was accompanied by detailed density functional theory calculations and variable-temperature solid-state deuteron NMR measurements indicating that interactions between the linking groups of the hydrogen-bond accepting unit play a key role in the chiral induction.
Anion-π Interaction: An Influential Force in Solid State Molecular Microstructures
The crystal structures of simple triphenyl(pentafluorobenzyl)phosphonium salts provide crucial data on the influence of anion size on the molecular structure of bis(pentafluorobenzyl)phosphonium cations containing two adjacent electron-deficient moieties. Whereas the bromide anions interact by anion-π interaction in a 1:1 mode with the pentafluorobenzene unit Z-configured, the bulkier anions iodide, tetrafluoroborate, and hexafluorophosphate result in a 1:2 tweezer-like anti-configuration in which one anion interacts simultaneously with two pentafluorobenzene units. When spatial separation of the two electron-deficient rings match the size of the anion, anion-π interactions induce a conform…
Geometrically diverse anions in anion–π interactions
The role of different anion geometries in anion–π interactions is discussed. The chemistry described herein is different to the interaction of spherical cations with aromatics. The influence of different geometries makes selective anion recognition more complicated than respective cation sensing. The present structural study reveals attractive interactions between pentafluorophenyl units and geometrically diverse anions (linear, trigonal planar, tetrahedral and octahedral). Due to the electrostatic nature of anion–π interactions, the anion geometry seems to be irrelevant. The size of the anion controls the relative orientation of the anion and the π system (e.g. in compounds 1–3). The dimer…
CCDC 967090: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 915608: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 1866422: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Matthias Spengler, Michael Pfletscher, Kim Kuntze, Matti Virkki, Christoph Wölper, Robert Gehrke, Georg Jansen, Pierangelo Metrangolo, Arri Priimagi, Michael Giese|2019|Chem.Mater.|31|462|doi:10.1021/acs.chemmater.8b04197
CCDC 1005283: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1894901: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K
CCDC 967091: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 955438: Experimental Crystal Structure Determination
Related Article: Zhan-Hu Sun, Markus Albrecht, Michael Giese, Fangfang Pan, Kari Rissanen|2014|Synlett|25|2075|doi:10.1055/s-0034-1378449
CCDC 1005269: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1005280: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1005278: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 936269: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Tatjana Repenko, Johannes Sackmann, Arto Valkonen, Kari Rissanen|2014|Eur.J.Org.Chem.|2014|2435|doi:10.1002/ejoc.201301336
CCDC 936267: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Tatjana Repenko, Johannes Sackmann, Arto Valkonen, Kari Rissanen|2014|Eur.J.Org.Chem.|2014|2435|doi:10.1002/ejoc.201301336
CCDC 1005287: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 915600: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 915601: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 915607: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 1939466: Experimental Crystal Structure Determination
Related Article: Meik Blanke, Jan Balszuweit, Marco Saccone, Christoph Wölper, David Doblas Jiménez, Markus Mezger, Jens Voskuhl, Michael Giese|2020|Chem.Commun.|56|1105|doi:10.1039/C9CC07721A
CCDC 1893331: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K
CCDC 1895359: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K
CCDC 1005272: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1886744: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Michael Pfletscher, Sven Kather, Christoph Wölper, Constantin Daniliuc, Markus Mezger, Michael Giese|2019|J.Mater.Chem.C|7|8643|doi:10.1039/C9TC02787D
CCDC 1895646: Experimental Crystal Structure Determination
Related Article: Andreas Kapf, Hassan Eslahi, Meik Blanke, Marco Saccone, Michael Giese, Marcel Albrecht|2019|New J.Chem.|43|6361|doi:10.1039/C9NJ00652D
CCDC 1005277: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1939467: Experimental Crystal Structure Determination
Related Article: Meik Blanke, Jan Balszuweit, Marco Saccone, Christoph Wölper, David Doblas Jiménez, Markus Mezger, Jens Voskuhl, Michael Giese|2020|Chem.Commun.|56|1105|doi:10.1039/C9CC07721A
CCDC 967092: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 915606: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 915603: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 967128: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Christian Bohnen, Tatjana Repenko, Arto Valkonen, Kari Rissanen|2014|Dalton Trans.|43|1873|doi:10.1039/C3DT52960F
CCDC 1895424: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K
CCDC 967093: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 915605: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2013|Eur.J.Org.Chem.|2013|3247|doi:10.1002/ejoc.201201704
CCDC 1866421: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Matthias Spengler, Michael Pfletscher, Kim Kuntze, Matti Virkki, Christoph Wölper, Robert Gehrke, Georg Jansen, Pierangelo Metrangolo, Arri Priimagi, Michael Giese|2019|Chem.Mater.|31|462|doi:10.1021/acs.chemmater.8b04197
CCDC 967129: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Christian Bohnen, Tatjana Repenko, Arto Valkonen, Kari Rissanen|2014|Dalton Trans.|43|1873|doi:10.1039/C3DT52960F
CCDC 1455700: Experimental Crystal Structure Determination
Related Article: Michael Pfletscher, Christoph Wölper, Jochen S. Gutmann, Markus Mezger, Michael Giese|2016|Chem.Commun.|52|8549|doi:10.1039/C6CC03966A
CCDC 936265: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Tatjana Repenko, Johannes Sackmann, Arto Valkonen, Kari Rissanen|2014|Eur.J.Org.Chem.|2014|2435|doi:10.1002/ejoc.201301336
CCDC 1005267: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1942435: Experimental Crystal Structure Determination
Related Article: Jan Balszuweit, Meik Blanke, Marco Saccone, Markus Mezger, Constantin G. Daniliuc, Christoph Wölper, Michael Giese, Jens Voskuhl|2021|MSDE|6|390|doi:10.1039/D0ME00171F
CCDC 936268: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Tatjana Repenko, Johannes Sackmann, Arto Valkonen, Kari Rissanen|2014|Eur.J.Org.Chem.|2014|2435|doi:10.1002/ejoc.201301336
CCDC 967097: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 967088: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 1005275: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 967089: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 967095: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 1895645: Experimental Crystal Structure Determination
Related Article: Andreas Kapf, Hassan Eslahi, Meik Blanke, Marco Saccone, Michael Giese, Marcel Albrecht|2019|New J.Chem.|43|6361|doi:10.1039/C9NJ00652D
CCDC 1005268: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1877494: Experimental Crystal Structure Determination
Related Article: Steffen Riebe, Marco Saccone, Jacqueline Stelzer, Andrea Sowa, Christoph Wölper, Kateryna Soloviova, Cristian A. Strassert, Michael Giese, Jens Voskuhl|2019|Chem.Asian J.|14|814|doi:10.1002/asia.201801564
CCDC 1871602: Experimental Crystal Structure Determination
Related Article: Steffen Riebe, Marco Saccone, Jacqueline Stelzer, Andrea Sowa, Christoph Wölper, Kateryna Soloviova, Cristian A. Strassert, Michael Giese, Jens Voskuhl|2018|CSD Communication|||
CCDC 1005281: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1886743: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Michael Pfletscher, Sven Kather, Christoph Wölper, Constantin Daniliuc, Markus Mezger, Michael Giese|2019|J.Mater.Chem.C|7|8643|doi:10.1039/C9TC02787D
CCDC 1945777: Experimental Crystal Structure Determination
Related Article: Jan Balszuweit, Meik Blanke, Marco Saccone, Markus Mezger, Constantin G. Daniliuc, Christoph Wölper, Michael Giese, Jens Voskuhl|2021|MSDE|6|390|doi:10.1039/D0ME00171F
CCDC 1005286: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 967096: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 936266: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Tatjana Repenko, Johannes Sackmann, Arto Valkonen, Kari Rissanen|2014|Eur.J.Org.Chem.|2014|2435|doi:10.1002/ejoc.201301336
CCDC 1871491: Experimental Crystal Structure Determination
Related Article: Steffen Riebe, Marco Saccone, Jacqueline Stelzer, Andrea Sowa, Christoph Wölper, Kateryna Soloviova, Cristian A. Strassert, Michael Giese, Jens Voskuhl|2019|Chem.Asian J.|14|814|doi:10.1002/asia.201801564
CCDC 1938656: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Meik Blanke, Constantin G. Daniliuc, Heikki Rekola, Jacqueline Stelzer, Arri Priimagi, Jens Voskuhl, Michael Giese|2019|ACS Materials Lett.|1|589|doi:10.1021/acsmaterialslett.9b00371
CCDC 1005273: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1005276: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1866420: Experimental Crystal Structure Determination
Related Article: Marco Saccone, Matthias Spengler, Michael Pfletscher, Kim Kuntze, Matti Virkki, Christoph Wölper, Robert Gehrke, Georg Jansen, Pierangelo Metrangolo, Arri Priimagi, Michael Giese|2019|Chem.Mater.|31|462|doi:10.1021/acs.chemmater.8b04197
CCDC 1001536: Experimental Crystal Structure Determination
Related Article: Zhan-Hu Sun, Markus Albrecht, Michael Giese, Fangfang Pan, Kari Rissanen|2014|Synlett|25|2075|doi:10.1055/s-0034-1378449
CCDC 967094: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087
CCDC 1005289: Experimental Crystal Structure Determination
Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K
CCDC 1005270: Experimental Crystal Structure Determination
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CCDC 1005279: Experimental Crystal Structure Determination
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CCDC 915602: Experimental Crystal Structure Determination
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CCDC 915604: Experimental Crystal Structure Determination
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CCDC 1005285: Experimental Crystal Structure Determination
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CCDC 1005284: Experimental Crystal Structure Determination
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CCDC 1005282: Experimental Crystal Structure Determination
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CCDC 1005271: Experimental Crystal Structure Determination
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CCDC 967127: Experimental Crystal Structure Determination
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CCDC 1005288: Experimental Crystal Structure Determination
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CCDC 967130: Experimental Crystal Structure Determination
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CCDC 915599: Experimental Crystal Structure Determination
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CCDC 1005274: Experimental Crystal Structure Determination
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