Kinetik und Molekulargewichtsverteilung eines anionischen Polymerisationsprozesses mit momentanem Start bei simultanem Monomerabbruch

6533b855fe1ef96bd12b07f9

RESEARCH PRODUCT

Kinetik und Molekulargewichtsverteilung eines anionischen Polymerisationsprozesses mit momentanem Start bei simultanem Monomerabbruch

subject

chemistry.chemical_compound Colloid and Surface Chemistry Monomer Anionic addition polymerization Polymers and Plastics Polymerization chemistry Kinetics Polymer chemistry Materials Chemistry Molar mass distribution Physical and Theoretical Chemistry

description

Die Kinetik und die Molekulargewichtsverteilung wird fur einen anionischen Polymerisationsprozes mit einem momentanen Startschritt und mit simultanem Monomerabbruch berechnet. Ein derartiger Polymerisationsablauf ist bei der anionischen Polymerisation von Methylmethacrylat in polaren Losungsmitteln zu erwarten. — Die Molekulargewichtsverteilung geht mit steigendem Monomerabbruch in eine SCHULZ-FLORY-Verteilung uber. The kinetics and the molecular weight distribution are calculated for an anionic polymerization with rapid initiation and simultaneous deactivation by the monomer. Such a process is to be expected for the anionic polymerization of methylmethacrylate in polar solvents. — The molecular weight distribution approaches a SCHULZ-FLORY-distribution with increasing monomer deactivation.

year	journal	country	edition	language
1973-11-07	Colloid and Polymer Science

https://doi.org/10.1007/bf02352239

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