6533b856fe1ef96bd12b1cea

RESEARCH PRODUCT

Optimisation of metallic interconnects for hydrogen production by high temperature water vapour electrolysis

I. PopaSébastien ChevalierYves WoutersMaria Rosa ArdigoValérie ParryWalairat Chandra-ambhornP. Phakpeetinan

subject

Materials scienceHydrogenALLOYS020209 energychemistry.chemical_element02 engineering and technology7. Clean energyCorrosionlaw.inventionELECTRICAL-CONDUCTIVITYlawCHROMIUM0202 electrical engineering electronic engineering information engineeringSCALE ADHERENCEGeneral Materials ScienceOXIDATION-KINETICSHydrogen productionOXIDE FUEL-CELLSElectrolysisRadiationHigh-temperature corrosionMetallurgy021001 nanoscience & nanotechnologyCondensed Matter PhysicsAnodechemistryHigh-temperature electrolysisCR2O30210 nano-technologyGROWTH MECHANISMSCRPolymer electrolyte membrane electrolysis

description

For economical and environmental reasons, hydrogen is considered as a major energetic vector for the future. Hydrogen production via high temperature water vapour electrolysis (HTE) is a promising technology. A major technical difficulty related to high temperature water vapour electrolysis is the development of interconnects working efficiently for a long period. Working temperature of 800°C enables the use of metallic materials as interconnects. Chromia forming alloys are among the best candidates. The interconnect material chosen in the present study is a ferritic stainless steel with 18% chromium content. High temperature corrosion resistance and electrical conductivity of the alloy was tested in both cathode (H2/H2O) and anode (O2/H2O) atmospheres. Corrosion products were then characterized by SEM-EDX and XRD. Moreover chromium evaporation measurements were carried out under anode atmosphere.

10.4028/www.scientific.net/ddf.323-325.239https://hal.archives-ouvertes.fr/hal-00750036