ChemInform Abstract: Triazolopyridines. Part 11. Ylides Derived from 2- Acylmethyltriazolopyridinium Salts.

6533b856fe1ef96bd12b251a

RESEARCH PRODUCT

ChemInform Abstract: Triazolopyridines. Part 11. Ylides Derived from 2- Acylmethyltriazolopyridinium Salts.

Fatemeh Mojarrad R. Ballesteros Gumos Jones B. Abarca M. R. Metni Enrique Pérez-carreño Santiago García-granda

subject

Dimethyl acetylenedicarboxylate Ethyl propiolate chemistry.chemical_compound Chemistry Organic chemistry General Medicine Medicinal chemistry Adduct

description

Abstract Ylides derived from 2-acylmethyltriazolopyridinium salts (2a) -(2c) react with methyl or ethyl propiolate and with dimethyl acetylenedicarboxylate to give ylides (3a)–(3e), (6) or (7). In some cases 1:2 adducts are formed, shown to be the novel ylides (8a)–(8d); an X-ray diffraction confirms structure (8a).

year	journal	country	edition	language
2010-08-22	ChemInform

https://doi.org/10.1002/chin.199140152

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