Author: Gumos Jones

0000000000528243

AUTHOR

Gumos Jones

Triazolopyridines. Part 11. Ylides derived from 2-Acylmethyltriazolopyridinium salts.

Abstract Ylides derived from 2-acylmethyltriazolopyridinium salts (2a) -(2c) react with methyl or ethyl propiolate and with dimethyl acetylenedicarboxylate to give ylides (3a)–(3e), (6) or (7). In some cases 1:2 adducts are formed, shown to be the novel ylides (8a)–(8d); an X-ray diffraction confirms structure (8a).

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ChemInform Abstract: Triazolopyridines. Part 11. Ylides Derived from 2- Acylmethyltriazolopyridinium Salts.

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