Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

6533b857fe1ef96bd12b3886

RESEARCH PRODUCT

Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

Hermas R. Jiménez Javier Pitarch-jarque Salvador Blasco Enrique García-españa M. Paz Clares Elina Kalenius Alberto Lopera Kari Rissanen

subject

Internal cavity Halide chemistry.chemical_element Pyrazole Combinatorial chemistry Chloride Copper Encapsulation (networking)Ion Inorganic Chemistry chemistry.chemical_compound chemistry medicine medicine.drug

description

A self-assembled metallobox from copper(ii) and two macrocycles containing 1H-pyrazole ligands has been prepared. The internal cavity of the box is able to selectively encapsulate a single chloride anion over any other halide anion.

year	journal	country	edition	language
2021-01-01	Dalton Transactions

https://doi.org/10.1039/d1dt01302e

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