Antivirale Wirkstoffe, 20. Mitt. 4,6-Dialkylierte 2-Benzylthiopyrimidine

6533b857fe1ef96bd12b42b4

RESEARCH PRODUCT

Antivirale Wirkstoffe, 20. Mitt. 4,6-Dialkylierte 2-Benzylthiopyrimidine

Swanhild Leyke-röhling Alfred Kreutzberger

subject

Aqueous solution Trifluoromethyl Ethanol Pyrimidine Stereochemistry Pharmaceutical Science Ether medicine.disease_cause Potassium carbonate chemistry.chemical_compound chemistry Drug Discovery Influenza A virus medicine

description

Aus der Kondensation von Benzylisothioharnstoff (1) mit den β-Diketonen 2a–c gehen die 2-Benzylthiopyrimidine 3a–c hervor. Wird die Reaktion 1+2b jedoch in 30proz. wasr. Kaliumcarbonat-Losung/Ethanol/Ether durchgefuhrt, so tritt unter Ethanolyse Bildung von 2-Ethoxy-4,6-diethylpyrimidin (4) ein. 2-Benzylthio-4-ethyl-6-(trifluormethyl)pyrimidin ubt Hemmwirkung gegen Influenza A-Virus aus. Antiviral Agents, XX: 4,6-Dialkylated 2-Benzylthiopyrimidines Condensations of benzylisothiourea (1) with the β-diketones 2a–c yield the 4,6-dialkylated 2-benzylthiopyrimidines 3a–c. However, in 30% aqueous potassium carbonate solution/ethanol/ether, the reaction 1+2b proceeds by ethanolysis to form 2-ethoxy-4,6-diethylpyrimidine (4). 2-Benzylthio-4-ethyl-6-(trifluoromethyl)pyrimidine exhibits inhibitory activity toward influenza A virus.

year	journal	country	edition	language
1981-01-01	Archiv der Pharmazie

https://doi.org/10.1002/ardp.19813141102

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