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RESEARCH PRODUCT

Self-Healing Properties of Bioinspired Amorphous CaCO3/Polyphosphate-Supplemented Cement

Werner E. G. M�llerMaximilian AckermannRafael Muñoz-espíEmad TolbaBothaina M. Abd El-hadyMeik NeufurthXiaohong WangHeinz C. SchröderShunfeng Wang

subject

Materials sciencePortland cementnanoindentationPharmaceutical Science02 engineering and technology010402 general chemistry01 natural sciencesAnalytical ChemistryCorrosionlaw.invention3-point bendinglcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistrylawDrug Discoveryself-healingPhysical and Theoretical ChemistryComposite materialCementCalcitePolyphosphateOrganic ChemistrypolyphosphateNanoindentation021001 nanoscience & nanotechnologyAmorphous calcium carbonate0104 chemical sciencesPortland cementsurgical procedures operativechemistryChemistry (miscellaneous)amorphous calcium carbonateHardening (metallurgy)Molecular Medicinemicrocrack formation0210 nano-technologycalcite

description

There is a strong interest in cement additives that are able to prevent or mitigate the adverse effects of cracks in concrete that cause corrosion of the reinforcement. Inorganic polyphosphate (polyP), a natural polymer that is synthesized by bacteria, even those on cement/concrete, can increase the resistance of concrete to progressive damage from micro-cracking. Here we use a novel bioinspired strategy based on polyP-stabilized amorphous calcium carbonate (ACC) to give this material self-healing properties. Portland cement was supplemented with ACC nanoparticles which were stabilized with 10% (w/w) Na&ndash

10.3390/molecules25102360https://www.mdpi.com/1420-3049/25/10/2360