6533b858fe1ef96bd12b6192

RESEARCH PRODUCT

Estimation of hydrogen transfer mechanisms in composite materials

Guntars VaivarsJānis KleperisL. GrinbergaG. BajarsA. Lusis

subject

Thermogravimetric analysisMaterials scienceHydrogenHydrideBorosilicate glassComposite numberchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsCatalysisHydrogen storagechemistryGeneral Materials ScienceComposite materialPowder diffraction

description

Abstract Spill-over effect as a hydrogen transfer mechanism is proposed to explain an increased capacity of hydrogen absorption and improvement of hydrogen activation kinetics in composite material based on the AB5 type metal hydride and powdered glass. A raw lanthanum nickel alloy AB5 with small amount of additives was used as catalyst and bulk material for hydrogen storage, and a borosilicate glass powder with developed surface was applied as a support material. Thermogravimetric technique to determine an absorbed amount of the hydrogen in materials and X-ray powder diffraction analysis for structural investigations was used.

https://doi.org/10.1016/j.ssi.2007.12.051