6533b859fe1ef96bd12b83a2
RESEARCH PRODUCT
Mono-, di- and tri-nuclear Ni(II) complexes of N-, O-donor ligands: structural diversity and reactivity
Chebrolu P. RaoMishtu DeyKari RissanenPauli Saarenketosubject
StereochemistryChemistryN- O-Donor MoleculesCrystal structureUrea AdductAdductInorganic ChemistryCrystallographychemistry.chemical_compoundPyridineMaterials ChemistryUreaMono- Di- And Tri-Nuclear Ni(Ii) ComplexesMoleculeReactivity (chemistry)Physical and Theoretical ChemistryAbsorption (chemistry)Pyridine Bound Mononuclear Ni(Ii) ComplexSingle crystaldescription
A series of mono-, di- and tri-nuclear Ni(II) complexes of N, O-donating molecules possessing ---H2C---NH--- and ---HC=N--- moieties have been synthesized and characterized and the structures have been determined by single crystal X-ray diffraction. All these exhibited interesting molecular packing in their crystal lattices. Di-nuclear complexes were found to be cleaved in pyridine to result in mononuclear ones with additional coordinations being provided by pyridine. Di-nuclear complexes were found to form urea adducts as demonstrated based on absorption and vibrational studies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-10-01 | Inorganic Chemistry Communications |