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RESEARCH PRODUCT

The controlled growth of GaN microrods on Si(111) substrates by MOCVD

Martin ValloHolger KalischMichael HeukenNúria GarroMatthias FinkenAndrés CantareroBartosz FoltynskiAndrei VescanC. Giesen

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Materials sciencePhotoluminescenceScanning electron microscopebusiness.industryNanotechnologyChemical vapor depositionCondensed Matter PhysicsSilaneInorganic ChemistryCrystalFull width at half maximumsymbols.namesakechemistry.chemical_compoundchemistryMaterials ChemistrysymbolsOptoelectronicsMetalorganic vapour phase epitaxybusinessRaman spectroscopy

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Abstract In this paper, a selective area growth (SAG) approach for growing GaN microrods on patterned SiN x /Si(111) substrates by metal-organic chemical vapor deposition (MOCVD) is studied. The surface morphology, optical and structural properties of vertical GaN microrods terminated by pyramidal shaped facets (six { 10 1 ¯ 1 } planes) were characterized using scanning electron microscopy (SEM), room temperature photoluminescence (PL) and Raman spectroscopy, respectively. Measurements revealed high-quality GaN microcolumns grown with silane support. Characterized structures were grown nearly strain-free (central frequency of Raman peak of 567±1 cm −1 ) with crystal quality comparable to bulk crystals (FWHM=4.2±1 cm −1 ). Such GaN microrods might be used as a next-generation device concept for solid-state lighting (SSL) applications by realizing core-shell InGaN/GaN multi-quantum wells (MQWs) on the n -GaN rod base.

https://doi.org/10.1016/j.jcrysgro.2014.10.047