6533b85bfe1ef96bd12bb2b7

RESEARCH PRODUCT

Microanalysis of the surfaces of natural iron-based minerals by means of synchrotron radiation based experimental techniques

J. MoraisT.a FazanGerhard H. FecherGerhard H. FecherOliver G. Schmidt

subject

X-ray absorption spectroscopyAbsorption spectroscopyIron oxideAnalytical chemistryMineralogySurfaces and InterfacesHematiteengineering.materialCondensed Matter PhysicsMicroanalysisSurfaces Coatings and Filmschemistry.chemical_compoundchemistryvisual_artMaterials Chemistryvisual_art.visual_art_mediumBorniteengineeringPyrrhotiteMagnetite

description

We investigated the surfaces of natural iron-based minerals that are magnetite, hematite, goethite, pyrite, pyrrhotite, chalcopyrite, bornite and vivianite, using synchrotron radiation based techniques. Most iron chalkogenides are very suitable for photoemission microscopy studies due to their low resistivity, which prevents from surface charging. The local compositions were studied employing photoemission microscopy in combination with X-ray absorption spectroscopy. Imaging of the sample in the near-edge region of the absorption edges was used to visualise the spatial distributions of the chemical phases on the surface. Distributions of trace elements are imaged with high chemical and lateral resolution.

https://doi.org/10.1016/s0039-6028(00)01027-x