Zur Chemie des Ecdysons, V: Versuche zur Darstellung von Steroid‐Δ 7 ‐6‐ketonen mit 3.4‐Diol‐Gruppierung

6533b85cfe1ef96bd12bc81f

RESEARCH PRODUCT

Zur Chemie des Ecdysons, V: Versuche zur Darstellung von Steroid‐Δ 7 ‐6‐ketonen mit 3.4‐Diol‐Gruppierung

Clemens Rufer Hans Hoffmeister Martin Traut Hans Schairer

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Ein milder Syntheseweg zu Steroid-Δ7-6-ketonen fuhrt uber Δ5.7-Diene. Cholestadien-(5.7)-diol-(3β.4α)-diacetat konnte dargestellt werden. Das entsprechende Dien-(5.7)-diol-(3β.4β) war nicht erhaltlich; aus 7α-Brom- bzw. 7-Hydroxy-cholesten-(5)-diol-(3β.4β)-Derivaten lies sich kein Halogenwasserstoff bzw. Wasser abspalten. Cholestan-diol-(3β.4β)-on-(6)-diacetat wurde synthetisiert.

year	journal	country	edition	language
1965-07-01	Chemische Berichte

https://doi.org/10.1002/cber.19650980742

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