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RESEARCH PRODUCT
Synthesis and Structure of a Potassium Potassiochromate: A Bis-Chromium(II) Molecule Held Together by Near-Square-Planar Potassium−Ligand Bridges
Christoph FörsterEva RentschlerLuca M. CarrellaJan KlettRobert E. MulveyAlan R. Kennedysubject
Steric effectsLigandMetalationChemistryPotassiumOrganic ChemistryCationic polymerizationchemistry.chemical_elementAte complexPhotochemistryInorganic ChemistryCrystallographyMoietyMoleculePhysical and Theoretical Chemistrydescription
No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-07-09 | Organometallics |