6533b85dfe1ef96bd12bde85

RESEARCH PRODUCT

Designing fluorous domains. Synthesis of a series of pyridinium salts bearing a perfluoroalkylated azole moiety

Nicolò VivonaLuciana MalpezziN. VivonaSilvestre BuscemiIvana PibiriAndrea Pace

subject

PharmacologyDouble layer (biology)chemistry.chemical_classificationMELTSCRYSTALChemistryDERIVATIVESPHOTOCHEMISTRYOrganic ChemistryFLUORINATED HETEROCYCLIC-COMPOUNDS124-TriazoleEXPEDIENT ROUTEAnalytical ChemistryCrystalIodide saltchemistry.chemical_compoundLIGHTIONIC LIQUIDSOXADIAZOLEPolymer chemistryMoietyOrganic chemistryAzolePyridiniumPOLYMERS

description

The synthesis of a series of N-methylpyridinium salts bearing a perfluoroalkylated 1,2,4-oxadiazole or 1,2,4-triazole moiety is reported. X-Ray structures of representative perfluoroalkyl-triazolylpyridine (15) and methyl- pyridinium iodide salt (5a) are reported. Their crystal packing clearly shows segregation between the aromatic and parallel double layer fluorinated regions.

10.3987/com-05-10633http://hdl.handle.net/10447/25536