6533b85dfe1ef96bd12be8e1

RESEARCH PRODUCT

18O-labeled interstitial oxygen molecules as probes to study reactions involving oxygen-related species in amorphous SiO2

Koichi KajiharaLinards SkujaLinards SkujaHideo Hosono

subject

Primary (chemistry)PhotoluminescenceIsotopeChemistryInorganic chemistrychemistry.chemical_elementCondensed Matter PhysicsOxygenElectronic Optical and Magnetic MaterialsAmorphous solidMaterials ChemistryCeramics and CompositesMoleculeExcess oxygenSpectroscopy

description

Abstract Isotope labeling has been widely used to study reactions involving oxygen species in amorphous SiO 2 ( a -SiO 2 ). This article briefly describes recent progress in 18 O labeling techniques to study reactions involving interstitial oxygen molecules (O 2 ), which is one of the most important excess oxygen species in a -SiO 2 . The primary focus will be on the combination of the 18 O labeling with photoluminescence spectroscopy, which enables sensitive and selective detection of interstitial O 2 . Advantages of this method and results of evaluation of oxygen exchange between interstitial O 2 and the Si―O network of a -SiO 2 will be presented.

10.1016/j.jnoncrysol.2012.04.038http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100646023