6533b85ffe1ef96bd12c117e
RESEARCH PRODUCT
Combining Spontaneous Polymerization and Click Reactions for the Synthesis of Polymer Brushes: A "Grafting Onto" Approach
Salvatore BattiatoAndrea CappelliFilippo SamperiFederica CastriconiEugenio PaccagniniGermano GiulianiGaetano GiammonaAntonella Caterina BocciaGiorgio GrisciStefania LamponiSalvatore VomeroRaniero MendichiAlessandro DonatiMariano LicciardiMariangela GentileMarco Paolinosubject
Magnetic Resonance Spectroscopypolymerclick reactionsCyclopentanesCatalysisCatalysisPolymerizationchemistry.chemical_compoundMolecular recognitionphotograftingPolymer chemistryClick reactionpolymerschemistry.chemical_classificationorganic chemicalsOrganic Chemistryfood and beveragesGeneral ChemistryPolymerGraftingMonomerchemistryPolymerizationpontaneous polymerizationPropargylPhotograftingSolventsClick Chemistrymolecular recognitiondescription
Two novel benzofulvene monomers bearing propargyl or allyl groups have been synthesized by means of readily accessible reactions, and were found to polymerize spontaneously by solvent removal, in the apparent absence of catalysts or initiators, to give the corresponding polybenzofulvene derivatives bearing clickable propargyl or allyl moieties. The clickable propargyl and allyl groups were exploited in appropriate click reactions to develop a powerful and versatile "grafting onto" synthetic methodology for obtaining tailored polymer brushes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-01-01 |