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RESEARCH PRODUCT

Should TiO2 nanostructures doped with Li+ be used as photoanodes for photoelectrochemical water splitting applications?

Rita Sánchez TovarE. Blasco-tamaritRamón Manuel Fernández DomeneBianca Lucas-granadosJose Garcia-anton

subject

Annealing (metallurgy)Nanotechnology02 engineering and technology010402 general chemistry01 natural sciencesCatalysisINGENIERIA QUIMICAAnnealingsymbols.namesakechemistry.chemical_compoundMicroscopyPhysical and Theoretical ChemistryWater splittingPhotocurrentNanoestructuresbusiness.industryChemistryEnergy conversion efficiencyDoping021001 nanoscience & nanotechnology0104 chemical sciencesNanostructuresElectroquímicaTitanium dioxidesymbolsWater splittingOptoelectronicsTitanium dioxideLi+ insertion0210 nano-technologybusinessRaman spectroscopy

description

[EN] Different TiO2 nanostructures, nanotubes and nanosponges, were obtained by anodization of Ti under stagnant and hydrodynamic conditions. Samples were doped with Li+ before and after annealing at 450 degrees C during 1 h. The nanostructures were characterized by different microscopy techniques: Field Emission Scanning Electron Microscopy (FE-SEM) and Raman Confocal Laser Microscopy. Additionally, Incident Photon-to-electron Conversion Efficiency (IPCE), photoelectrochemical water splitting and stability measurements were also performed. According to the results, TiO2 nanostructures doped before annealing present the worst photocurrent response, even if compared with undoped samples. On the other hand, this study reveals that Li+-doped TiO2 nanostructures doped after annealing can be used as durable and stable photoanodes for photoelectrochemical water splitting applications. (C) 2017 Elsevier Inc. All rights reserved.

yearjournalcountryeditionlanguage
2017-05-01
10.1016/j.jcat.2017.03.001https://hdl.handle.net/10550/76847