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RESEARCH PRODUCT
Complexes of organometallic compounds
Friedo HuberHans PreutArturo SilvestriLorenzo PelleritoHans-jürgen HauptRenato BarbieriF. Di BlancaRosalba Cefalùsubject
InfraredStereochemistryOrganic Chemistrychemistry.chemical_elementBiochemistryOxygenSulfurInorganic ChemistryTrigonal bipyramidal molecular geometrychemistry.chemical_compoundCrystallographyMonomerOctahedronchemistryMössbauer spectroscopyMaterials ChemistryPhysical and Theoretical ChemistryGroup 2 organometallic chemistrydescription
Abstract Novel complexes RClSntrid, where R is Me, Ph, n-Oct, and trid 2− are dianions of tridentate “planar” ligands with ONO and SNO donor atoms, were synthesized and investigated in the solid state by infrared and Mossbauer spectroscopy. Possible configurations are discussed; polymeric trigonal bipyramidal structures seem to occur, although five-coordinated monomers as well as octahedral dimers (via oxygen or sulfur bridges) are not excluded.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1974-09-01 | Journal of Organometallic Chemistry |