6533b860fe1ef96bd12c3a89
RESEARCH PRODUCT
Di-chlorido-[N-(N,N-di-methyl-carbamimido-yl)-N',N',4-tri-methyl-benzohydrazonamide]-platinum(II) nitro-methane hemisolvate.
Nadezha A. BokachMatti HaukkaDmitrii S. Bolotinsubject
Metal-Organic PapersCrystallographySolvent moleculeNitromethane010405 organic chemistryChemistryHydrogen bondBent molecular geometryGeneral Chemistry010402 general chemistryCondensed Matter PhysicsBioinformaticsRing (chemistry)01 natural sciencesMedicinal chemistry3. Good health0104 chemical sciencesCrystalchemistry.chemical_compoundQD901-999AtomGeneral Materials ScienceConjugatedescription
In the title compound, [PtCl2(C13H21N5)]·0.5CH3NO2, the PtIIatom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-triazapentadiene)PtIImetalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N—H...Cl hydrogen bonds link the complex molecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-01-03 | Acta crystallographica. Section E, Structure reports online |