6533b861fe1ef96bd12c452a

RESEARCH PRODUCT

Aromatic N-oxide templates open inclusion and dimeric capsular assemblies with methylresorcinarene

Rakesh PuttreddyKari RissanenNgong Kodiah Beyeh

subject

General Chemical EngineeringQuinolineOxideSolid-statemacromolecular substancesGeneral Chemistryaromatic N-oxide templatesCrystallographychemistry.chemical_compoundTemplatechemistryPyridineSingle crystalta116Stoichiometry

description

C2-2-methylresorcinarene forms host–guest complexes with pyridine N-oxide and quinoline N-oxide. In solution the NMR studies support the 1 : 1 host–guest complexes while in the solid state, the single crystal X-ray diffraction studies reveal dimeric capsule-like assemblies with 2 : 3 and 2 : 2 host–guest stoichiometry.

10.1039/c5ra03667dhttps://doi.org/10.1039/c5ra03667d