6533b861fe1ef96bd12c58e8

RESEARCH PRODUCT

N-{4-[(3-Methyl-phen-yl)sulfamo-yl]phen-yl}benzamide.

Jyonthi DamodaraManu LahtinenErkki KolehmainenPoornima UpadhyayaNonappa

subject

CrystallographyHydrogen bondAromaticityGeneral ChemistryDihedral angleCondensed Matter PhysicsBioinformaticsRing (chemistry)Organic PapersCrystalchemistry.chemical_compoundCrystallographychemistryQD901-999AmideGeneral Materials ScienceBenzamideBenzeneta116

description

In the title compound, C20H18N2O3S, the dihedral angle between the central benzene ring and the amide group is 24.1 (3)° and that between this ring and the aromatic ring of the tolyl group is 68.2 (16)°. In the crystal, adjacent molecules are linked by N—H...O hydrogen bonds into a linear chain running along [100]. Weak C—H...O contacts also occur. Extensive weak π–π interactions exist from both face-to-face and face-to-edge interactions occur between the aromatic rings [centroid–centroid distances = 3.612 (2) and 4.843 (2) Å].

10.1107/s1600536811040384https://pubmed.ncbi.nlm.nih.gov/22219906