6533b862fe1ef96bd12c6340

RESEARCH PRODUCT

Effect of pseudo-gravitational acceleration on the dissolution rate of miscible drops

Tatiana La MonicaJohn A. PojmanRenato LombardoGloria Viner

subject

Mass fluxConvectionMaterials scienceBuoyancyApplied MathematicsDrop (liquid)General Physics and AstronomyThermodynamicsStatistical and Nonlinear Physics02 engineering and technologyengineering.material021001 nanoscience & nanotechnologyGravitational acceleration01 natural sciencesOrganic compounds Equipment and apparatus Mass diffusion Gravity waves G factorMass transfer0103 physical sciencesengineering010306 general physics0210 nano-technologyTransport phenomenaDissolutionMathematical PhysicsSettore CHIM/02 - Chimica Fisica

description

The effect of pseudo-gravitational acceleration on the dissolution process of two phase miscible systems has been investigated at high acceleration values using a spinning drop tensiometer with three systems: 1-butanol/water, isobutyric acid/water, and triethylamine/water. We concluded that the dissolution process involves at least three different transport phenomena: diffusion, barodiffusion, and gravitational (buoyancy-driven) convection. The last two phenomena are significantly affected by the centrifugal acceleration acting at the interface between the two fluids, and the coupling with the geometry of the dissolving drop leads to a change of the mass flux during the course of the dissolution process.

https://doi.org/10.1063/1.4990069