6533b862fe1ef96bd12c647d

RESEARCH PRODUCT

Formation of a micropatterned titania photocatalyst by microcontact printed silicatein on gold surfaces

Matthias WiensWerner E. G. M�llerTarek A. ElkhoolyThorben LinkSimone Isbert

subject

TitaniumMaterials scienceSurface PropertiesUltraviolet RaysMetals and AlloysNanotechnology02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCathepsins01 natural sciencesRecombinant ProteinsCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMicrocontact printingMaterials ChemistryCeramics and CompositesPhotocatalysisSurface modificationGold0210 nano-technology

description

The enzyme silicatein has been bioengineered to carry a thiol-bearing Au-affinity tag (Cys-tag) for direct immobilization on gold carriers in shortest time without the need for prior surface functionalization. Through microcontact printing, defined silicatein micropatterns were created on gold surfaces, facilitating the subsequent enzymatically controlled synthesis of photocatalytically active TiO(2).

https://doi.org/10.1039/c2cc35977d