6533b86cfe1ef96bd12c899a

RESEARCH PRODUCT

Pentakis(dimethylzinn)diphosphid, struktur und kernresonanzspektren eines zinnreichen bicyclus

Bernd Mathiasch

subject

chemistry.chemical_classificationBicyclic moleculeStereochemistryWhite PhosphorusOrganic ChemistryBiochemistryMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundchemistryHeterocyclic compoundMaterials ChemistryMoleculeDehydrogenationPhysical and Theoretical ChemistryNorbornane

description

Abstract Dehydrogenation of dimethylstannane combined with the hydrostannolysis of white phosphorus yields pentakis(dimethyltin) diphosphide, a tin-rich heterocyclic compound, which has the highly symmetric, bicyclic molecular structure of norbornane. Using the X-ray structure data the magnetic resonance spectra are discussed.

yearjournalcountryeditionlanguage
1979-02-01Journal of Organometallic Chemistry
https://doi.org/10.1016/s0022-328x(00)82198-1