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RESEARCH PRODUCT
A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)
Ari LehtonenOula WichmannRathna Durga R.s. ManianReko Leinosubject
Ligandchemistry.chemical_elementChiral diamineInorganic Chemistrychemistry.chemical_compoundMonomerOxygen atomchemistryMolybdenumTripodal ligandDiaminePolymer chemistryMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryTetradentate liganddescription
Abstract A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO2(acac)2] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-10-01 | Inorganic Chemistry Communications |