6533b86efe1ef96bd12cbc54
RESEARCH PRODUCT
Dendritic octa-CMPO derivatives of calix[4]arenes
Pingshan WangJean-françois DozolValéry HostMohamed SaadiouiVolker BöhmerChristian SchmidtJean F. Desreuxsubject
Aqueous solutionLigandOrganic ChemistryInorganic chemistryEtherBiochemistryMetalchemistry.chemical_compoundchemistryNitric acidDendrimervisual_artDrug DiscoveryPolymer chemistryProton NMRvisual_art.visual_art_mediumTitrationdescription
Abstract Calix[4]arenes substituted at the narrow or wide rim by eight carbamoylmethyl-phosphine oxide (CMPO) functions in a dendritic manner were synthesised and studied in extraction of Eu 3+ and Am 3+ from aqueous nitric acid into o -nitrophenylhexyl ether. 1 H NMR relaxivity titrations for a wide rim octa-CMPO reveal the clear formation of a solvent-free 1:2 ligand/metal complex, while the wide rim tetra-CMPO formed oligomeric complexes under similar conditions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-03-01 | Tetrahedron |