6533b86efe1ef96bd12cca84
RESEARCH PRODUCT
One-pot synthesis and characterization of subnanometre-size benzotriazolate protected copper clusters
Hannu HäkkinenKirsi SalorinneRalf W. TroffXi ChenMaija Nissinensubject
ta114Inorganic chemistryOne-pot synthesischemistry.chemical_elementInfrared spectroscopyTriazolesMass spectrometryCopperCharacterization (materials science)CrystallographychemistryCoordination ComplexesTransmission electron microscopyQuantum TheorySpectrophotometry UltravioletGeneral Materials ScienceStructural motifta116Copperdescription
A simple one-pot method for the preparation of subnanometre-size benzotriazolate (BTA) protected copper clusters, Cu(n)BTA(m), is reported. The clusters were analyzed by optical and infrared spectroscopy, mass spectrometry and transmission electron microscopy together with computational methods. We suggest a structural motif where the copper core of the Cu(n)BTA(m) clusters is protected by BTA-Cu(i)-BTA units.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-04-26 | Nanoscale |