Observation of light-by-light scattering in ultraperipheral Pb+Pb collisions with the ATLAS detector

This Letter describes the observation of the light-by-light scattering process, γγ→γγ, in Pb+Pb collisions at √sNN=5.02  TeV. The analysis is conducted using a data sample corresponding to an integrated luminosity of 1.73  nb−1, collected in November 2018 by the ATLAS experiment at the LHC. Light-by-light scattering candidates are selected in events with two photons produced exclusively, each with transverse energy EγT>3  GeV and pseudorapidity |ηγ|<2.4, diphoton invariant mass above 6 GeV, and small diphoton transverse momentum and acoplanarity. After applying all selection criteria, 59 candidate events are observed for a background expectation of 12±3 events. The observed excess of events…

Search for squarks and gluinos in final states with jets and missing transverse momentum using 36  fb−1 of s=13  TeV pp collision data with the ATLAS detector

A search for the supersymmetric partners of quarks and gluons (squarks and gluinos) in final states containing hadronic jets and missing transverse momentum, but no electrons or muons, is presented ...

Measurement of the top pair production cross section in 8 TeV proton-proton collisions using kinematic information in thelepton+jetsfinal state with ATLAS

A measurement is presented of the (tt) over bar inclusive production cross section in pp collisions at a center-ofmass energy of pffisffiffi root s = 8 TeV using data collected by the ATLAS detector at the CERN Large Hadron Collider. The measurement was performed in the lepton + jets final state using a data set corresponding to an integrated luminosity of 20.3 fb(-1). The cross section was obtained using a likelihood discriminant fit and b-jet identification was used to improve the signal-to-background ratio. The inclusive (tt) over bar production cross section was measured to be 260 +/- 1(stat)(-23)(+22)(stat) +/- 8(lumi) +/- 4(beam) pb assuming a top-quark mass of 172.5 GeV, in good agre…

A Unified AMBER-Compatible Molecular Mechanics Force Field for Thiolate-Protected Gold Nanoclusters.

We present transferable AMBER-compatible force field parameters for thiolate-protected gold nanoclusters. Five different sized clusters containing both organo-soluble and water-soluble thiolate ligands served as test systems in MD simulations, and parameters were validated against DFT and experimental results. The cluster geometries remain intact during the MD simulations in various solvents, and structural fluctuations and energetics showed agreement with DFT calculations. Experimental diffusion coefficients and crystal structures were also reproduced with sufficient accuracy. The presented parameter set contains the minimum number of cluster-specific parameters enabling the use of these p…

Evidence ofWγγProduction inppCollisions ats=8  TeVand Limits on Anomalous Quartic Gauge Couplings with the ATLAS Detector

This Letter reports evidence of triple gauge boson production pp -> W(l nu)gamma gamma + X, which is accessible for the first time with the 8 TeV LHC data set. The fiducial cross section for this process is measured in a data sample corresponding to an integrated luminosity of 20.3 fb(-1), collected by the ATLAS detector in 2012. Events are selected using the W boson decay to e nu or mu nu as well as requiring two isolated photons. The measured cross section is used to set limits on anomalous quartic gauge couplings in the high diphoton mass region.

Comparison of Fragmentation Functions for Jets Dominated by Light Quarks and Gluons from pp and Pb+Pb Collisions in ATLAS

Charged-particle fragmentation functions for jets azimuthally balanced by a high-transverse-momentum, prompt, isolated photon are measured in 25  pb^{-1} of pp and 0.49  nb^{-1} of Pb+Pb collision data at 5.02 TeV per nucleon pair recorded with the ATLAS detector at the Large Hadron Collider. The measurements are compared to predictions of Monte Carlo generators and to measurements of inclusively selected jets. In pp collisions, a different jet fragmentation function in photon-tagged events from that in inclusive jet events arises from the difference in fragmentation between light quarks and gluons. The ratios of the fragmentation functions in Pb+Pb events to that in pp events are used to e…

Nonmagnetic and magnetic thiolate-protected Au25superatoms on Cu(111), Ag(111), and Au(111) surfaces

Geometry, electronic structure, and magnetic properties of methylthiolate-stabilized Au$_{25}$L$_{18}$ and MnAu$_{24}$L$_{18}$ (L = SCH$_3$) clusters adsorbed on noble-metal (111) surfaces have been investigated by using spin-polarized density functional theory computations. The interaction between the cluster and the surface is found to be mediated by charge transfer mainly from or into the ligand monolayer. The electronic properties of the 13-atom metal core remain in all cases rather undisturbed as compared to the isolated clusters in gas phase. The Au$_{25}$L$_{18}$ cluster retains a clear HOMO - LUMO energy gap in the range of 0.7 eV to 1.0 eV depending on the surface. The ligand layer…

Ca2+ signalling plays a role in celastrol‐mediated suppression of synovial fibroblasts of rheumatoid arthritis patients and experimental arthritis in rats

Background and purpose Celastrol exhibits anti-arthritic effects in rheumatoid arthritis (RA), but the role of celastrol-mediated Ca2+ mobilization in treatment of RA remains undefined. Here, we describe a regulatory role for celastrol-induced Ca2+ signalling in synovial fibroblasts of RA patients and adjuvant-induced arthritis (AIA) in rats. Experimental approach We used computational docking, Ca2+ dynamics and functional assays to study the sarcoplasmic/endoplasmic reticulum Ca2+ ATPase pump (SERCA). In rheumatoid arthritis synovial fibroblasts (RASFs)/rheumatoid arthritis fibroblast-like synoviocytes (RAFLS), mechanisms of Ca2+ -mediated autophagy were analysed by histological, immunohis…

Search for top squarks decaying to tau sleptons in pp collisions at s=13  TeV with the ATLAS detector

A search for direct pair production of top squarks in final states with two tau leptons, b-jets, and missing transverse momentum is presented. The analysis is based on proton-proton collision data ...

Search for New Phenomena in Final States with Two Leptons and One or No b -Tagged Jets at s=13  TeV Using the ATLAS Detector

A search for new phenomena is presented in final states with two leptons and one or no $b$-tagged jets. The event selection requires the two leptons to have opposite charge, the same flavor (electrons or muons), and a large invariant mass. The analysis is based on the full Run-2 proton-proton collision dataset recorded at a center-of-mass energy of $\sqrt{s} = 13$ TeV by the ATLAS experiment at the LHC, corresponding to an integrated luminosity of 139 fb$^{-1}$. No significant deviation from the expected background is observed in the data. A four-fermion contact interaction between two quarks ($b,s$) and two leptons ($ee$ or $\mu\mu$), inspired by the $B$-meson decay anomalies, is used as a…

Search for dark matter in association with a Higgs boson decaying to two photons at s=13  TeV with the ATLAS detector

A search for dark matter in association with a Higgs boson decaying to two photons is presented. This study is based on data collected with the ATLAS detector, corresponding to an integrated lumino ...

Measurements ofW±Zproduction cross sections inppcollisions ats=8  TeVwith the ATLAS detector and limits on anomalous gauge boson self-couplings

This paper presents measurements of W(+/-)Z production in pp collisions at a center-of-mass energy of 8 TeV. The gauge bosons are reconstructed using their leptonic decay modes into electrons and m ...

Search for flavor-changing neutral currents in top quark decays t→Hc and t→Hu in multilepton final states in proton-proton collisions at s=13  TeV with the ATLAS detector

Flavor-changing neutral currents are not present in the Standard Model at tree level and are suppressed in loop processes by the unitarity of the Cabibbo-Kobayashi-Maskawa matrix; the corresponding ...

Search for new phenomena in events with a photon and missing transverse momentum inppcollisions ats=8  TeVwith the ATLAS detector

© 2015 CERN. © 2015 CERN, for the ATLAS Collaboration. Published by the American Physical Society under the terms of the »http://creativecommons.org/licenses/by/3.0/» Creative Commons Attribution 3.0 License. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI. Results of a search for new phenomena in events with an energetic photon and large missing transverse momentum with the ATLAS experiment at the LHC are reported. Data were collected in proton-proton collisions at a center-of-mass energy of 8 TeV and correspond to an integrated luminosity of 20.3 fb-1. The observed data are well described by the expe…

Search for Higgs Boson Decays into a Z Boson and a Light Hadronically Decaying Resonance Using 13 TeV pp Collision Data from the ATLAS Detector

A search for Higgs boson decays into a Z boson and a light resonance in two-lepton plus jet events is performed, using a pp collision dataset with an integrated luminosity of 139  fb^{-1} collected at sqrt[s]=13  TeV by the ATLAS experiment at the CERN LHC. The resonance considered is a light boson with a mass below 4 GeV from a possible extended scalar sector or a charmonium state. Multivariate discriminants are used for the event selection and for evaluating the mass of the light resonance. No excess of events above the expected background is found. Observed (expected) 95% confidence-level upper limits are set on the Higgs boson production cross section times branching fraction to a Z bos…

Measurements ofWγandZγproduction inppcollisions ats=7  TeVwith the ATLAS detector at the LHC

The integrated and differential fiducial cross sections for the production of a W or Z boson in association with a high-energy photon are measured using pp collisions at root s = 7 TeV. The analyse ...

Dijet Resonance Search with Weak Supervision Using s=13  TeV pp Collisions in the ATLAS Detector

This Letter describes a search for narrowly resonant new physics using a machine-learning anomaly detection procedure that does not rely on signal simulations for developing the analysis selection. Weakly supervised learning is used to train classifiers directly on data to enhance potential signals. The targeted topology is dijet events and the features used for machine learning are the masses of the two jets. The resulting analysis is essentially a three-dimensional search A→BC, for m_{A}∼O(TeV), m_{B},m_{C}∼O(100  GeV) and B, C are reconstructed as large-radius jets, without paying a penalty associated with a large trials factor in the scan of the masses of the two jets. The full run 2 sq…

Searches for Higgs boson pair production in thehh→bbττ,γγWW*,γγbb,bbbbchannels with the ATLAS detector

Searches for both resonant and nonresonant Higgs boson pair production are performed in the hh -> bb tau tau, gamma gamma WW* final states using 20.3 fb(-1) of pp collision data at a center-of-m ...

Protective Role for LPA3 in Cardiac Hypertrophy Induced by Myocardial Infarction but Not by Isoproterenol

Background: We previously reported that lysophosphatidic acid (LPA) promoted cardiomyocyte hypertrophy in vitro via one of its G protein-coupled receptor subtypes, LPA3. In this study, we examined the role of LPA3 in cardiac hypertrophy induced by isoproterenol (ISO) and myocardial infarction. Methods: In vitro, neonatal rat cardiomyocytes (NRCMs) were subjected to LPA3 knocked-down, or pretreated with a β-adrenergic receptor (β-AR) antagonist (propranolol) before LPA/ISO treatment. Cardiomyocyte size and hypertrophic gene (ANP, BNP) mRNA levels were determined. In vivo, LPA3-/- and wild-type mice were implanted subcutaneously with an osmotic mini-pump containing ISO or vehicle for 2 weeks;…

Measurement of the transverse polarization ofΛandΛ¯hyperons produced in proton-proton collisions ats=7  TeVusing the ATLAS detector

The transverse polarization of Λ and Λ¯ hyperons produced in proton-proton collisions at a center-of-mass energy of 7 TeV is measured. The analysis uses 760  μb−1 of minimum bias data collected by the ATLAS detector at the LHC in the year 2010. The measured transverse polarization averaged over Feynman xF from 5×10−5 to 0.01 and transverse momentum pT from 0.8 to 15 GeV is −0.010±0.005(stat)±0.004(syst) for Λ and 0.002±0.006(stat)±0.004(syst) for Λ¯. It is also measured as a function of xF and pT, but no significant dependence on these variables is observed. Prior to this measurement, the polarization was measured at fixed-target experiments with center-of-mass energies up to about 40 GeV. …

Chemoselective Dual Labeling of Native and Recombinant Proteins

The attachment of two different functionalities in a site-selective fashion represents a great challenge in protein chemistry. We report site specific dual functionalizations of peptides and proteins capitalizing on reactivity differences of cysteines in their free (thiol) and protected, oxidized (disulfide) forms. The dual functionalization of interleukin 2 and EYFP proceeded with no loss of bioactivity in a stepwise fashion applying maleimide and disulfide rebridging allyl-sulfone groups. In order to ensure broader applicability of the functionalization strategy, a novel, short peptide sequence that introduces a disulfide bridge was designed and site-selective dual labeling in the presenc…

Search for Scalar Charm Quark Pair Production inppCollisions ats=8  TeVwith the ATLAS Detector

The results of a dedicated search for pair production of scalar partners of charm quarks are reported. The search is based on an integrated luminosity of 20.3 fb(-1) of pp collisions at root s = 8 TeV recorded with the ATLAS detector at the LHC. The search is performed using events with large missing transverse momentum and at least two jets, where the two leading jets are each tagged as originating from c quarks. Events containing isolated electrons or muons are vetoed. In an R-parity-conserving minimal super-symmetric scenario in which a single scalar-charm state is kinematically accessible, and where it decays exclusively into a charm quark and a neutralino, 95% confidence-level upper li…

Search for trilepton resonances from chargino and neutralino pair production in s=13  TeV pp collisions with the ATLAS detector

A search is performed for the electroweak pair production of charginos and associated production of a chargino and neutralino, each of which decays through an $R$-parity-violating coupling into a lepton and a $W$, $Z$, or Higgs boson. The trilepton invariant-mass spectrum is constructed from events with three or more leptons, targeting chargino decays that include an electron or muon and a leptonically decaying $Z$ boson. The analyzed dataset corresponds to an integrated luminosity of 139 fb$^{-1}$ of proton-proton collision data produced by the Large Hadron Collider at a center-of-mass energy of $\sqrt{s}$ = 13 TeV and collected by the ATLAS experiment between 2015 and 2018. The data are f…

Retrieving Quantum Information with Active Learning

Active learning is a machine learning method aiming at optimal design for model training. At variance with supervised learning, which labels all samples, active learning provides an improved model by labeling samples with maximal uncertainty according to the estimation model. Here, we propose the use of active learning for efficient quantum information retrieval, which is a crucial task in the design of quantum experiments. Meanwhile, when dealing with large data output, we employ active learning for the sake of classification with minimal cost in fidelity loss. Indeed, labeling only 5% samples, we achieve almost 90% rate estimation. The introduction of active learning methods in the data a…

Determination of the Ratio ofb-Quark Fragmentation Fractionsfs/fdinppCollisions ats=7  TeVwith the ATLAS Detector

With an integrated luminosity of 2.47 fb^{-1} recorded by the ATLAS experiment at the LHC, the exclusive decays B_{s}^{0}→J/ψϕ and B_{d}^{0}→J/ψK^{*0} of B mesons produced in pp collisions at sqrt[s]=7 TeV are used to determine the ratio of fragmentation fractions f_{s}/f_{d}. From the observed B_{s}^{0}→J/ψϕ and B_{d}^{0}→J/ψK^{*0} yields, the quantity (f_{s}/f_{d})[B(B_{s}^{0}→J/ψϕ)/B(B_{d}^{0}→J/ψK^{*0})] is measured to be 0.199±0.004(stat)±0.008(syst). Using a recent theory prediction for [B(B_{s}^{0}→J/ψϕ)/B(B_{d}^{0}→J/ψK^{*0})] yields (f_{s}/f_{d})=0.240±0.004(stat)±0.010(syst)±0.017(th). This result is based on a new approach that provides a significant improvement of the world aver…

Conformation and dynamics of the ligand shell of a water-soluble Au102 nanoparticle

Inorganic nanoparticles, stabilized by a passivating layer of organic molecules, form a versatile class of nanostructured materials with potential applications in material chemistry, nanoscale physics, nanomedicine and structural biology. While the structure of the nanoparticle core is often known to atomic precision, gaining precise structural and dynamical information on the organic layer poses a major challenge. Here we report a full assignment of 1H and 13C NMR shifts to all ligands of a water-soluble, atomically precise, 102-atom gold nanoparticle stabilized by 44 para-mercaptobenzoic acid ligands in solution, by using a combination of multidimensional NMR methods, density functional t…

Measurement of the correlation between flow harmonics of different order in lead-lead collisions at sNN=2.76 TeV with the ATLAS detector

Correlations between the elliptic or triangular flow coefficients v(m) (m = 2 or 3) and other flow harmonics v(n) (n = 2 to 5) are measured using root S-NN = 2.76 TeV Pb + Pb collision data collected in 2010 by the ATLAS experiment at the LHC, corresponding to an integrated luminosity of 7 mu b(-1). The v(m)-v(n) correlations aremeasured in midrapidity as a function of centrality, and, for events within the same centrality interval, as a function of event ellipticity or triangularity defined in a forward rapidity region. For events within the same centrality interval, v(3) is found to be anticorrelated with v(2) and this anticorrelation is consistent with similar anticorrelations between th…

Search for the Production of a Long-Lived Neutral Particle Decaying within the ATLAS Hadronic Calorimeter in Association with a Z Boson from pp Collisions at s=13  TeV

This Letter presents a search for the production of a long-lived neutral particle (Zd) decaying within the ATLAS hadronic calorimeter, in association with a standard model (SM) Z boson produced via an intermediate scalar boson, where Z→+ (=e, μ). The data used were collected by the ATLAS detector during 2015 and 2016 pp collisions with a center-of-mass energy of s=13 TeV at the Large Hadron Collider and correspond to an integrated luminosity of 36.1±0.8 fb-1. No significant excess of events is observed above the expected background. Limits on the production cross section of the scalar boson times its decay branching fraction into the long-lived neutral particle are derived as a function of …

Protected but Accessible: Oxygen Activation by a Calixarene-Stabilized Undecagold Cluster

DFT computations show that calixarenes stabilize subnanometer Au11 clusters allowing access of small molecules like O2 to reactive metal sites in the core. Maximum of three dioxygen molecules can bind to the cluster, and they are activated to a superoxo O2(-) state. This study predicts that gold clusters could act as viable oxidation catalysts at ambient conditions based on similar principles as the metal centers in enzymes.

A measurement of material in the ATLAS tracker using secondary hadronic interactions in 7 TeV pp collisions

Knowledge of the material in the ATLAS inner tracking detector is crucial in understanding the reconstruction of charged-particle tracks, the performance of algorithms that identify jets containing b-hadrons and is also essential to reduce background in searches for exotic particles that can decay within the inner detector volume. Interactions of primary hadrons produced in pp collisions with the material in the inner detector are used to map the location and amount of this material. The hadronic interactions of primary particles may result in secondary vertices, which in this analysis are reconstructed by an inclusive vertex-finding algorithm. Data were collected using minimum-bias trigger…

Search for Dark Matter in Events with Missing Transverse Momentum and a Higgs Boson Decaying to Two Photons inppCollisions ats=8  TeVwith the ATLAS Detector

Results of a search for new phenomena in events with large missing transverse momentum and a Higgs boson decaying to two photons are reported. Data from proton-proton collisions at a center-of-mass energy of 8 TeV and corresponding to an integrated luminosity of 20.3  fb−1 have been collected with the ATLAS detector at the LHC. The observed data are well described by the expected standard model backgrounds. Upper limits on the cross section of events with large missing transverse momentum and a Higgs boson candidate are also placed. Exclusion limits are presented for models of physics beyond the standard model featuring dark-matter candidates.

Search for resonances in the mass distribution of jet pairs with one or two jets identified as b-jets in proton–proton collisions at s=13 TeV with the ATLAS detector

Searches for high-mass resonances in the dijet invariant mass spectrum with one or two jets identified as $b$-jets are performed using an integrated luminosity of $3.2$ fb$^{-1}$ of proton--proton collisions with a centre-of-mass energy of $\sqrt{s}=13$ TeV recorded by the ATLAS detector at the Large Hadron Collider. No evidence of anomalous phenomena is observed in the data, which are used to exclude, at 95% credibility level, excited $b^{*}$ quarks with masses from 1.1 TeV to 2.1 TeV and leptophobic $Z'$ bosons with masses from 1.1 TeV to 1.5 TeV. Contributions of a Gaussian signal shape with effective cross sections ranging from approximately 0.4 to 0.001 pb are also excluded in the mass…

Search for heavy resonances decaying to a photon and a hadronically decaying Z/W/H boson in pp collisions at s=13  TeV with the ATLAS detector

This Letter presents a search for the production of new heavy resonances decaying into a Higgs boson and a photon using proton-proton collision data at √ s = 13     TeV collected by the ATLAS detector at the LHC. The data correspond to an integrated luminosity of 139     fb − 1 . The analysis is performed by reconstructing hadronically decaying Higgs boson ( H → b ¯ b ) candidates as single large-radius jets. A novel algorithm using information about the jet constituents in the center-of-mass frame of the jet is implemented to identify the two b quarks in the single jet. No significant excess of events is observed above the expected background. Upper limits are set on the production cross-s…

Search for Higgs bosons produced via vector-boson fusion and decaying into bottom quark pairs in s=13  TeV pp collisions with the ATLAS detector

A search for the b (b) over bar decay of the Standard Model Higgs boson produced through vector-boson fusion is presented. Three mutually exclusive channels are considered: two all-hadronic channel ...

Toward Prediction of Financial Crashes with a D-Wave Quantum Annealer

The prediction of financial crashes in a complex financial network is known to be an NP-hard problem, which means that no known algorithm can efficiently find optimal solutions. We experimentally explore a novel approach to this problem by using a D-Wave quantum annealer, benchmarking its performance for attaining a financial equilibrium. To be specific, the equilibrium condition of a nonlinear financial model is embedded into a higher-order unconstrained binary optimization (HUBO) problem, which is then transformed into a spin-1/2 Hamiltonian with at most, two-qubit interactions. The problem is thus equivalent to finding the ground state of an interacting spin Hamiltonian, which can be app…

Search for new phenomena in dijet events using 37  fb−1 of pp collision data collected at s=13  TeV with the ATLAS detector

Dijet events are studied in the proton-proton collision dataset recorded at root s = 13 TeV with the ATLAS detector at the Large Hadron Collider in 2015 and 2016, corresponding to integrated lumino ...

Measurement of the suppression and azimuthal anisotropy of muons from heavy-flavor decays in Pb+Pb collisions at sNN=2.76 TeV with the ATLAS detector

ATLAS measurements of the production of muons from heavy-flavor decays in root s(NN) = 2.76 TeV Pb+Pb collisions and root s = 2.76 TeV pp collisions at the LHC are presented. Integrated luminositie ...

Search for Higgs andZBoson Decays toJ/ψγandϒ(nS)γwith the ATLAS Detector

A search for the decays of the Higgs and Z bosons to J/psi gamma and Upsilon(nS)gamma (n = 1,2,3) is performed with pp collision data samples corresponding to integrated luminosities of up to 20.3 fb(-1) collected at root s = 8 TeV with the ATLAS detector at the CERN Large Hadron Collider. No significant excess of events is observed above expected backgrounds and 95% C.L. upper limits are placed on the branching fractions. In the J/psi gamma final state the limits are 1.5 x 10(-3) and 2.6 x 10(-6) for the Higgs and Z boson decays, respectively, while in the Upsilon(1S, 2S, 3S)gamma. final states the limits are (1.3, 1.9, 1.3) x 10(-3) and (3.4, 6.5, 5.4) x 10(-6), respectively.

Measurement of Spin Correlation in Top-Antitop Quark Events and Search for Top Squark Pair Production inppCollisions ats=8  TeVUsing the ATLAS Detector

A measurement of spin correlation in t (t) over bar production is presented using data collected with the ATLAS detector at the Large Hadron Collider in proton-proton collisions at a center-of-mass ...

Divide and Protect: Passivating Cu(111) by Cu-(benzotriazole)2

Binding of benzotriazolate anion (BTA) to copper complexes and Cu(111) surface was investigated by density functional theory calculations. [BTACuBTA]1– was found to be a very stable complex that BT...

Combination of the Searches for Pair-Produced Vectorlike Partners of the Third-Generation Quarks at s=13  TeV with the ATLAS Detector

A combination of the searches for pair-produced vectorlike partners of the top and bottom quarks in various decay channels (T -> Zt/Wb/Ht, B -> Zb/Wt/Hb) is performed using 36.1 fb(-1) of pp ...

Search for Higgs andZBoson Decays toϕγwith the ATLAS Detector

A search for the decays of the Higgs and Z bosons to a ϕ meson and a photon is performed with a pp collision data sample corresponding to an integrated luminosity of 2.7  fb^{-1} collected at sqrt[s]=13  TeV with the ATLAS detector at the LHC. No significant excess of events is observed above the background, and 95% confidence level upper limits on the branching fractions of the Higgs and Z boson decays to ϕγ of 1.4×10^{-3} and 8.3×10^{-6}, respectively, are obtained.

Study of ordered hadron chains with the ATLAS detector

The analysis of the momentum difference between charged hadrons in high-energy proton-proton collisions is performed in order to study coherent particle production. The observed correlation pattern agrees with a model of a helical QCD string fragmenting into a chain of ground-state hadrons. A threshold momentum difference in the production of adjacent pairs of charged hadrons is observed, in agreement with model predictions. The presence of low-mass hadron chains also explains the emergence of charge-combination-dependent two-particle correlations commonly attributed to Bose-Einstein interference. The data sample consists of 190 μb-1 of minimum-bias events collected with proton-proton colli…

Search for type-III seesaw heavy leptons inppcollisions ats=8  TeVwith the ATLAS detector

A search for the pair production of heavy leptons (N-0, L-+/-) predicted by the type-III seesaw theory formulated to explain the origin of small neutrino masses is presented. The decay channels N-0 -> W(+/-)l(+/-) (l = e, mu, tau) and L-+/- -> W(+/-)v (v = v(e), v(mu), v(tau)) are considered. The analysis is performed using the final state that contains two leptons (electrons or muons), two jets from a hadronically decaying W boson and large missing transverse momentum. The data used in the measurement correspond to an integrated luminosity of 20.3 fb(-1) of pp collisions at root s = 8 TeV collected by the ATLAS detector at the LHC. No evidence of heavy lepton pair production is observed. H…

Longitudinal Flow Decorrelations in Xe+Xe Collisions at sNN=5.44  TeV with the ATLAS Detector

The first measurement of longitudinal decorrelations of harmonic flow amplitudes v_{n} for n=2-4 in Xe+Xe collisions at sqrt[s_{NN}]=5.44  TeV is obtained using 3  μb^{-1} of data with the ATLAS detector at the LHC. The decorrelation signal for v_{3} and v_{4} is found to be nearly independent of collision centrality and transverse momentum (p_{T}) requirements on final-state particles, but for v_{2} a strong centrality and p_{T} dependence is seen. When compared with the results from Pb+Pb collisions at sqrt[s_{NN}]=5.02  TeV, the longitudinal decorrelation signal in midcentral Xe+Xe collisions is found to be larger for v_{2}, but smaller for v_{3}. Current hydrodynamic models reproduce th…

Toward Pricing Financial Derivatives with an IBM Quantum Computer

Pricing interest-rate financial derivatives is a major problem in finance, in which it is crucial to accurately reproduce the time evolution of interest rates. Several stochastic dynamics have been proposed in the literature to model either the instantaneous interest rate or the instantaneous forward rate. A successful approach to model the latter is the celebrated Heath-Jarrow-Morton framework, in which its dynamics is entirely specified by volatility factors. In its multifactor version, this model considers several noisy components to capture at best the dynamics of several time-maturing forward rates. However, as no general analytical solution is available, there is a trade-off between t…

Search for massive, long-lived particles using multitrack displaced vertices or displaced lepton pairs inppcollisions ats=8  TeVwith the ATLAS detector

Many extensions of the Standard Model posit the existence of heavy particles with long lifetimes. This article presents the results of a search for events containing at least one long-lived particle that decays at a significant distance from its production point into two leptons or into five or more charged particles. This analysis uses a data sample of proton-proton collisions at root s = 8 TeV corresponding to an integrated luminosity of 20.3 fb(-1) collected in 2012 by the ATLAS detector operating at the Large Hadron Collider. No events are observed in any of the signal regions, and limits are set on model parameters within supersymmetric scenarios involving R-parity violation, split sup…

A computer‐based Pinyin intervention for disadvantaged children in China : Effects on Pinyin skills, phonological awareness, and character reading

Pinyin is an alphabetic script that denotes pronunciations of Chinese characters. Studies have shown that Pinyin instruction enhances both phonological awareness (e.g., Shu et al., Developmental Science, 2008, 11, 171–181) and character reading (e.g., Lin et al., Psychological Science, 2010, 21, 1117–1122) in Chinese children. In the present study, we provided a 3‐week Pinyin intervention with a computer‐based Pinyin GraphoGame to disadvantaged migrant children with poor Pinyin skills. A total of 252 first graders who were children of migrant workers in a large Chinese city were assessed to identify poor Pinyin readers. Fifty‐six 7‐year‐old children with poor Pinyin skills were selected and…

Synthesis, computational docking and biological evaluation of celastrol derivatives as dual inhibitors of SERCA and P-glycoprotein in cancer therapy.

Abstract A series of eleven celastrol derivatives was designed, synthesized, and evaluated for their in vitro cytotoxic activities against six human cancer cell lines (A549, HepG2, HepAD38, PC3, DLD-1 Bax-Bak WT and DKO) and three human normal cells (LO2, BEAS-2B, CCD19Lu). To our knowledge, six derivatives were the first example of dipeptide celastrol derivatives. Among them, compound 3 was the most promising derivative, as it exhibited a remarkable anti-proliferative activity and improved selectivity in liver cancer HepAD38 versus human normal hepatocytes, LO2. Compound 6 showed higher selectivity in liver cancer cells against human normal lung fibroblasts, CCD19Lu cell line. The Ca2+ mob…

Search for a Charged Higgs Boson Produced in the Vector-Boson Fusion Mode with DecayH±→W±ZusingppCollisions ats=8  TeVwith the ATLAS Experiment

A search for a charged Higgs boson, H-+/-, decaying to a W-+/- boson and a Z boson is presented. The search is based on 20.3 fb(-1) of proton-proton collision data at a center-of-mass energy of 8 TeV recorded with the ATLAS detector at the LHC. The H-+/- boson is assumed to be produced via vector-boson fusion and the decays W-+/- -> q (q') over bar and Z -> e(+)e(-)/mu(+)mu(-) are considered. The search is performed in a range of charged Higgs boson masses from 200 to 1000 GeV. No evidence for the production of an H+ boson is observed. Upper limits of 31-1020 fb at 95% C.L. are placed on the cross section for vector-boson fusion production of an H-+/- boson times its branching fraction to W…

Search for supersymmetry in events with four or more leptons in s=13  TeV pp collisions with ATLAS

Results from a search for supersymmetry in events with four or more charged leptons (electrons, muons and taus) are presented. The analysis uses a data sample corresponding to 36.1 fb-1 of proton-proton collisions delivered by the Large Hadron Collider at s=13 TeV and recorded by the ATLAS detector. Four-lepton signal regions with up to two hadronically decaying taus are designed to target a range of supersymmetric scenarios that can be either enriched in or depleted of events involving the production and decay of a Z boson. Data yields are consistent with Standard Model expectations and results are used to set upper limits on the event yields from processes beyond the Standard Model. Exclu…

Core‐Selective Silver‐Doping of Gold Nanoclusters by Surface‐Bound Sulphates on Colloidal Templates: From Synthetic Mechanism to Relaxation Dynamics

Funding Information: This work was carried out under the ERC Advanced grant (DRIVEN, ERC‐2016‐AdG‐742829), Academy of Finland's Centre of Excellence in Life‐Inspired Hybrid Materials (LIBER, 346108), Academy of Finland (No. 321443, 328942, 308647, and 318891) and Photonic Research and Innovation (PREIN) as well as FinnCERES flagships. L.F. and X.C. thanks for support from CSC (IT Center for Science, Finland) for providing computation resources. The authors acknowledge the provision of facilities and technical support by Aalto University OtaNano – Nanomicroscopy Center (Aalto‐NMC). | openaire: EC/H2020/742829/EU//DRIVEN Ultra-small luminescent gold nanoclusters (AuNCs) have gained substantia…

Observation of Centrality-Dependent Acoplanarity for Muon Pairs Produced via Two-Photon Scattering in Pb+Pb Collisions at sNN=5.02  TeV with the ATLAS Detector

This Letter presents a measurement of γγ→μ^{+}μ^{-} production in Pb+Pb collisions recorded by the ATLAS detector at the Large Hadron Collider at sqrt[s_{NN}]=5.02  TeV with an integrated luminosity of 0.49  nb^{-1}. The azimuthal angle and transverse momentum correlations between the muons are measured as a function of collision centrality. The muon pairs are produced from γγ through the interaction of the large electromagnetic fields of the nuclei. The contribution from background sources of muon pairs is removed using a template fit method. In peripheral collisions, the muons exhibit a strong back-to-back correlation consistent with previous measurements of muon pair production in ultrap…

Experimentally Realizing Efficient Quantum Control with Reinforcement Learning

Robust and high-precision quantum control is crucial but challenging for scalable quantum computation and quantum information processing. Traditional adiabatic control suffers severe limitations on gate performance imposed by environmentally induced noise because of a quantum system's limited coherence time. In this work, we experimentally demonstrate an alternative approach {to quantum control} based on deep reinforcement learning (DRL) on a trapped $^{171}\mathrm{Yb}^{+}$ ion. In particular, we find that DRL leads to fast and robust {digital quantum operations with running time bounded by shortcuts to adiabaticity} (STA). Besides, we demonstrate that DRL's robustness against both Rabi and…

Search for photonic signatures of gauge-mediated supersymmetry in 8TeV pp collisions with the ATLAS detector

A search is presented for photonic signatures motivated by generalized models of gauge-mediated supersymmetry breaking. This search makes use of 20.3  fb[superscript −1] of proton-proton collision data at √s = 8  TeV recorded by the ATLAS detector at the LHC, and explores models dominated by both strong and electroweak production of supersymmetric partner states. Four experimental signatures incorporating an isolated photon and significant missing transverse momentum are explored. These signatures include events with an additional photon, lepton, b-quark jet, or jet activity not associated with any specific underlying quark flavor. No significant excess of events is observed above the Stand…

CP Properties of Higgs Boson Interactions with Top Quarks in the tt¯H and tH Processes Using H→γγ with the ATLAS Detector

A study of the charge conjugation and parity (CP) properties of the interaction between the Higgs boson and top quarks is presented. Higgs bosons are identified via the diphoton decay channel (H→γγ), and their production in association with a top quark pair (tt[over ¯]H) or single top quark (tH) is studied. The analysis uses 139  fb^{-1} of proton-proton collision data recorded at a center-of-mass energy of sqrt[s]=13  TeV with the ATLAS detector at the Large Hadron Collider. Assuming a CP-even coupling, the tt[over ¯]H process is observed with a significance of 5.2 standard deviations. The measured cross section times H→γγ branching ratio is 1.64_{-0.36}^{+0.38}(stat)_{-0.14}^{+0.17}(sys) …

Measurement of Azimuthal Anisotropy of Muons from Charm and Bottom Hadrons in pp Collisions at s=13  TeV with the ATLAS Detector

The elliptic flow of muons from the decay of charm and bottom hadrons is measured in pp collisions at sqrt[s]=13  TeV using a data sample with an integrated luminosity of 150  pb^{-1} recorded by the ATLAS detector at the LHC. The muons from heavy-flavor decay are separated from light-hadron decay muons using momentum imbalance between the tracking and muon spectrometers. The heavy-flavor decay muons are further separated into those from charm decay and those from bottom decay using the distance-of-closest-approach to the collision vertex. The measurement is performed for muons in the transverse momentum range 4-7 GeV and pseudorapidity range |η|<2.4. A significant nonzero elliptic anisotro…

Single Crystal Sub‐Nanometer Sized Cu6(SR)6 Clusters: Structure, Photophysical Properties, and Electrochemical Sensing

Organic ligand-protected metal nanoclusters have attracted extensively attention owing to their atomically precise composition, determined atom-packing structure and the fascinating properties and promising applications. To date, most research has been focused on thiol-stabilized gold and silver nanoclusters and their single crystal structures. Here the single crystal copper nanocluster species (Cu6(SC7H4NO)6) determined by X-ray crystallography and mass spectrometry is presented. The hexanuclear copper core is a distorted octahedron surrounded by six mercaptobenzoxazole ligands as protecting units through a simple bridging bonding motif. Density functional theory (DFT) calculations provide…

Medium-Induced Modification of Z -Tagged Charged Particle Yields in Pb+Pb Collisions at 5.02 TeV with the ATLAS Detector

The yield of charged particles opposite to a Z boson with large transverse momentum (p_{T}) is measured in 260  pb^{-1} of pp and 1.7  nb^{-1} of Pb+Pb collision data at 5.02 TeV per nucleon pair recorded with the ATLAS detector at the Large Hadron Collider. The Z boson tag is used to select hard-scattered partons with specific kinematics, and to observe how their showers are modified as they propagate through the quark-gluon plasma created in Pb+Pb collisions. Compared with pp collisions, charged-particle yields in Pb+Pb collisions show significant modifications as a function of charged-particle p_{T} in a way that depends on event centrality and Z boson p_{T}. The data are compared with a…

Search for bottom-squark pair production in pp collision events at s=13  TeV with hadronically decaying τ -leptons, b -jets, and missing transverse momentum using the ATLAS detector

A search for pair production of bottom squarks in events with hadronically decaying τ-leptons, b-tagged jets, and large missing transverse momentum is presented. The analyzed dataset is based on proton-proton collisions at s=13 TeV delivered by the Large Hadron Collider and recorded by the ATLAS detector from 2015 to 2018, and corresponds to an integrated luminosity of 139 fb-1. The observed data are compatible with the expected Standard Model background. Results are interpreted in a simplified model where each bottom squark is assumed to decay into the second-lightest neutralino χ 20 and a bottom quark, with χ 20 decaying into a Higgs boson and the lightest neutralino χ 10. The search focu…

Observation of a Charged Charmoniumlike Structure in e+e−→π+π−J/ψ at s=4.26 GeV

Gold Au(I)6 Clusters with Ligand-Derived Atomic Steric Locking: Multifunctional Optoelectrical Properties and Quantum Coherence

Funding Information: This work was supported by the ERC Advanced grant (DRIVEN, ERC‐2016‐AdG‐742829), the ERC grant (834742), the EU H2020‐MSCA‐RISE‐872049 (IPN‐Bio), the Academy of Finland's Centre of Excellence in Molecular Engineering of Biosynthetic Hybrid Materials Research (HYBER, 2014–2019), and Life‐Inspired Hybrid Materials (LIBER, 346108), Academy of Finland project fundings (No. 352900, 314810, 333982, 336144, 352780, 352930 and 353364), FinnCERES and Photonics Research and Innovation (PREIN) flagship programs. The authors acknowledge the provision of facilities and technical support by Aalto University OtaNano – Nanomicroscopy Center (Aalto‐NMC). | openaire: EC/H2020/834742/EU//…

Search for the Higgs boson decays H → ee and H → eμ in pp collisions at s=13TeV with the ATLAS detector

Searches for the Higgs boson decays H -> ee and H -> e mu are performed using data corresponding to an integrated luminosity of 139 fb(-1) collected with the ATLAS detector in pp collisions a ...

Measurement ofη′→π+π−e+e−andη′→π+π−μ+μ−

Based on a sample of 225.3 million $J/\ensuremath{\psi}$ events accumulated with the BESIII detector at the BEPCII, the decays of ${\ensuremath{\eta}}^{\ensuremath{'}}\ensuremath{\rightarrow}{\ensuremath{\pi}}^{+}{\ensuremath{\pi}}^{\ensuremath{-}}{l}^{+}{l}^{\ensuremath{-}}$ are studied via $J/\ensuremath{\psi}\ensuremath{\rightarrow}\ensuremath{\gamma}{\ensuremath{\eta}}^{\ensuremath{'}}$. A clear ${\ensuremath{\eta}}^{\ensuremath{'}}$ signal is observed in the ${\ensuremath{\pi}}^{+}{\ensuremath{\pi}}^{\ensuremath{-}}{e}^{+}{e}^{\ensuremath{-}}$ mass spectrum, and the branching fraction is measured to be $\mathcal{B}({\ensuremath{\eta}}^{\ensuremath{'}}\ensuremath{\rightarrow}{\ensuremat…

Search for invisible Higgs boson decays in vector boson fusion at s=13TeV with the ATLAS detector

We report a search for Higgs bosons that are produced via vector boson fusion and subsequently decay into invisible particles. The experimental signature is an energetic jet pair with invariant mass of O(1)TeV and O(100)GeV missing transverse momentum. The analysis uses 36.1 fb −1 of pp collision data at s=13TeV recorded by the ATLAS detector at the LHC. In the signal region the 2252 observed events are consistent with the background estimation. Assuming a 125GeV scalar particle with Standard Model cross sections, the upper limit on the branching fraction of the Higgs boson decay into invisible particles is 0.37 at 95% confidence level where 0.28 was expected. This limit is interpreted in H…

Measurement of the tt¯ production cross section in the τ+jets final state in pp collisions at s=8  TeV using the ATLAS detector

A measurement of the inclusive pp -> t (t) over bar + X production cross section in the tau + jets final state using only the hadronic decays of the tau lepton is presented. The measurement is p ...

Evidence for the production of three massive vector bosons with the ATLAS detector

A search for the production of three massive vector bosons in proton–proton collisions is performed using data at TeV recorded with the ATLAS detector at the Large Hadron Collider in the years 2015–2017, corresponding to an integrated luminosity of 79.8 fb−1. Events with two same-sign leptons ℓ (electrons or muons) and at least two reconstructed jets are selected to search for . Events with three leptons without any same-flavour opposite-sign lepton pairs are used to search for , while events with three leptons and at least one same-flavour opposite-sign lepton pair and one or more reconstructed jets are used to search for . Finally, events with four leptons are analysed to search for and .…

Autophagy

Klionsky, Daniel J. et al.

Test of CP invariance in vector-boson fusion production of the Higgs boson in the H → ττ channel in proton–proton collisions at s=13TeV with the ATLAS detector

A test of CP invariance in Higgs boson production via vector-boson fusion is performed in the H → ττ decay channel. This test uses the Optimal Observable method and is carried out using 36.1 fb−1 of √s = 13 TeV proton–proton collision data collected by the ATLAS experiment at the LHC. Contributions from CP-violating interactions between the Higgs boson and electroweak gauge bosons are described by an effective field theory, in which the parameter ˜ d governs the strength of CP violation. No sign of CP violation is observed in the distributions of the Optimal Observable, and ˜ d is constrained to the interval [−0.090, 0.035] at the 68% confidence level (CL), compared to an expected interval …

Search for Heavy Higgs Bosons Decaying into Two Tau Leptons with the ATLAS Detector Using pp Collisions at s=13  TeV

A search for heavy neutral Higgs bosons is performed using the LHC Run 2 data, corresponding to an integrated luminosity of 139  fb^{-1} of proton-proton collisions at sqrt[s]=13  TeV recorded with the ATLAS detector. The search for heavy resonances is performed over the mass range 0.2-2.5 TeV for the τ^{+}τ^{-} decay with at least one τ-lepton decaying into final states with hadrons. The data are in good agreement with the background prediction of the standard model. In the M_{h}^{125} scenario of the minimal supersymmetric standard model, values of tanβ>8 and tanβ>21 are excluded at the 95% confidence level for neutral Higgs boson masses of 1.0 and 1.5 TeV, respectively, where tanβ is the…

Observation of Electroweak Production of a Same-Sign W Boson Pair in Association with Two Jets in pp Collisions at s=13  TeV with the ATLAS Detector

This Letter presents the observation and measurement of electroweak production of a same-sign W boson pair in association with two jets using 36.1  fb^{-1} of proton-proton collision data recorded at a center-of-mass energy of sqrt[s]=13  TeV by the ATLAS detector at the Large Hadron Collider. The analysis is performed in the detector fiducial phase-space region, defined by the presence of two same-sign leptons, electron or muon, and at least two jets with a large invariant mass and rapidity difference. A total of 122 candidate events are observed for a background expectation of 69±7 events, corresponding to an observed signal significance of 6.5 standard deviations. The measured fiducial s…

Acid–Base Properties and Surface Charge Distribution of the Water-Soluble Au102(pMBA)44 Nanocluster

The pKa of the p-mercaptobenzoic acid (pMBA) ligands in the Au102(pMBA)44 nanocluster was measured by using acid–base and IR titration. The observed macroscopic pKa = 6.18 ± 0.05 is significantly more basic than that of free pMBA (pKa = 4.16), and the protonation behavior is anticooperative according to the Hill coefficient n = 0.64 ± 0.04. The cluster is truly water-soluble when more than 22 and insoluble when fewer than 7 ligands are in the deprotonated state. In order to obtain more insight into the anticooperative character, the cluster was modeled at pH ∼6.2 using constant pH molecular dynamics simulations. The pKa values of the individual pMBAs are in the range of 5.18–7.58, depending…

Combination of searches for heavy resonances decaying into bosonic and leptonic final states using 36  fb−1 of proton-proton collision data at s=13  TeV with the ATLAS detector

Searches for new heavy resonances decaying into different pairings of W, Z, or Higgs bosons, as well as dirffiffiffiectly into leptons, are presented using a data sample corresponding to 36.1 fb(-1 ...

Plasmonic twinned silver nanoparticles with molecular precision

Determining the structures of nanoparticles at atomic resolution is vital to understand their structure–property correlations. Large metal nanoparticles with core diameter beyond 2 nm have, to date, eluded characterization by single-crystal X-ray analysis. Here we report the chemical syntheses and structures of two giant thiolated Ag nanoparticles containing 136 and 374 Ag atoms (that is, up to 3 nm core diameter). As the largest thiolated metal nanoparticles crystallographically determined so far, these Ag nanoparticles enter the truly metallic regime with the emergence of surface plasmon resonance. As miniatures of fivefold twinned nanostructures, these structures demonstrate a subtle dis…

A New Fitness Test of Estimating VO2max in Well-Trained Rowing Athletes

BackgroundThis study was designed to investigate the validity of maximal oxygen consumption (VO2max) estimation through the Firstbeat fitness test (FFT) method when using submaximal rowing and running programs for well-trained athletes.MethodsWell-trained flatwater rowers (n = 45, 19.8 ± 3.0 years, 184 ± 8.7 cm, 76 ± 12.9 kg, and 58.7 ± 6.0 mL⋅kg–1⋅min–1) and paddlers (n = 45, 19.0 ± 2.5 years, 180 ± 7.7 cm, 74 ± 9.4 kg, and 59.9 ± 4.8 mL⋅kg–1⋅min–1) completed the FFT and maximal graded exercise test (GXT) programs of rowing and running, respectively. The estimated VO2max was calculated using the FFT system, and the measured VO2max was obtained from the GXT programs. Differences between the…

Search for high-mass diphoton resonances inppcollisions ats=8  TeVwith the ATLAS detector

Search for high-mass diphoton resonances in pp collisions at pffisffi root s=8 TeV with the ATLAS detector

Measurements of tt¯ differential cross-sections of highly boosted top quarks decaying to all-hadronic final states in pp collisions at s=13  TeV using the ATLAS detector

Measurements are made of differential cross-sections of highly boosted pair-produced top quarks as a function of top-quark and t (t) over bar system kinematic observables using proton-proton collis ...

Search for Dark Matter Produced in Association with a Dark Higgs Boson Decaying into W±W∓ or ZZ in Fully Hadronic Final States from s=13  TeV pp Collisions Recorded with the ATLAS Detector

Several extensions of the Standard Model predict the production of dark matter particles at the LHC. An uncharted signature of dark matter particles produced in association with VV=W^{±}W^{∓} or ZZ pairs from a decay of a dark Higgs boson s is searched for using 139  fb^{-1} of pp collisions recorded by the ATLAS detector at a center-of-mass energy of 13 TeV. The s→V(qq[over ¯])V(qq[over ¯]) decays are reconstructed with a novel technique aimed at resolving the dense topology from boosted VV pairs using jets in the calorimeter and tracking information. Dark Higgs scenarios with m_{s}>160  GeV are excluded.

Search for the standard model Higgs boson produced in association with a vector boson and decaying into a tau pair inppcollisions ats=8  TeVwith the ATLAS detector

A search for the standard model Higgs boson produced in association with a vector boson with the decay H -> tau tau is presented. The data correspond to 20.3 fb(-1) of integrated luminosity from proton-proton collisions at root s = 8 TeV recorded by the ATLAS experiment at the LHC during 2012. The data agree with the background expectation, and 95% confidence-level upper limits are placed on the cross section of this process. The observed (expected) limit, expressed in terms of the signal strength mu= sigma/sigma(SM) for m(H) = 125 GeV, is mu < 5.6 (3.7). The measured value of the signal strength is mu = 2.3 +/- 1.6.

Measurement of light-by-light scattering and search for axion-like particles with 2.2 nb−1 of Pb+Pb data with the ATLAS detector

We thank CERN for the very successful operation of the LHC, as well as the support staff from our institutions without whom ATLAS could not be operated efficiently. We acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWFW and FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq and FAPESP, Brazil; NSERC, NRC and CFI, Canada; CERN; ANID, Chile; CAS, MOST and NSFC, China; COLCIENCIAS, Colombia; MSMT CR, MPO CR and VSC CR, Czech Republic; DNRF and DNSRC, Denmark; IN2P3-CNRS and CEA-DRF/IRFU, France; SRNSFG, Georgia; BMBF, HGF and MPG, Germany; GSRT, Greece; RGC and Hong Kong SAR, China; ISF and Benoziyo Center, Israel; INFN, Italy; MEXT and JSPS, Japan; CNRST, Mor…

Robust control of unstable nonlinear quantum systems

Adiabatic passage is a standard tool for achieving robust transfer in quantum systems. We show that, in the context of driven nonlinear Hamiltonian systems, adiabatic passage becomes highly non-robust when the target is unstable. We show this result for a generic (1:2) resonance, for which the complete transfer corresponds to a hyperbolic fixed point in the classical phase space featuring an adiabatic connectivity strongly sensitive to small perturbations of the model. By inverse engineering, we devise high-fidelity and robust partially non-adiabatic trajectories. They localize at the approach of the target near the stable manifold of the separatrix, which drives the dynamics towards the ta…

Structural Evolution of Atomically Precise Thiolated Bimetallic [Au12+nCu32(SR)30+n]4– (n = 0, 2, 4, 6) Nanoclusters

A series of all-thiol stabilized bimetallic Au-Cu nanoclusters, [Au(12+n)Cu32(SR)(30+n)](4-) (n = 0, 2, 4, 6 and SR = SPhCF3), are successfully synthesized and characterized by X-ray single-crystal analysis and density functional theory (DFT) calculations. Each cluster consists of a Keplerate two-shell Au12@Cu20 core protected by (6 - n) units of Cu2(SR)5 and n units of Cu2Au(SR)6 (n = 0, 2, 4, 6) motifs on its surface. The size and structural evolution of the clusters is atomically controlled by the Au precursors and countercations used in the syntheses. The clusters exhibit similar optical absorption properties that are not dependent on the number of surface Cu2Au(SR)6 units. Although DFT…

Measurement of prompt photon production in sNN=8.16 TeV p + Pb collisions with ATLAS

The inclusive production rates of isolated, prompt photons in p+Pb collisions at sNN=8.16 TeV are studied with the ATLAS detector at the Large Hadron Collider using a dataset with an integrated luminosity of 165 nb −1 recorded in 2016. The cross-section and nuclear modification factor RpPb are measured as a function of photon transverse energy from 20 GeV to 550 GeV and in three nucleon–nucleon centre-of-mass pseudorapidity regions, (−2.83,−2.02) , (−1.84,0.91) , and (1.09,1.90) . The cross-section and RpPb values are compared with the results of a next-to-leading-order perturbative QCD calculation, with and without nuclear parton distribution function modifications, and with expectations b…

Search for Displaced Leptons in s=13  TeV pp Collisions with the ATLAS Detector

A search for charged leptons with large impact parameters using 139  fb^{-1} of sqrt[s]=13  TeV pp collision data from the ATLAS detector at the LHC is presented, addressing a long-standing gap in coverage of possible new physics signatures. Results are consistent with the background prediction. This search provides unique sensitivity to long-lived scalar supersymmetric lepton partners (sleptons). For lifetimes of 0.1 ns, selectron, smuon, and stau masses up to 720, 680, and 340  GeV, respectively, are excluded at 95% confidence level, drastically improving on the previous best limits from LEP.

Measurement of the production cross section for a Higgs boson in association with a vector boson in the H → WW⁎ → ℓνℓν channel in pp collisions at s=13 TeV with the ATLAS detector

A measurement of the Higgs boson production cross sections via associated WH and ZH production using H -> WW* -> l nu l nu decays, where l stands for either an electron or a muon, is presente ...

One-pot synthesis and characterization of subnanometre-size benzotriazolate protected copper clusters

A simple one-pot method for the preparation of subnanometre-size benzotriazolate (BTA) protected copper clusters, Cu(n)BTA(m), is reported. The clusters were analyzed by optical and infrared spectroscopy, mass spectrometry and transmission electron microscopy together with computational methods. We suggest a structural motif where the copper core of the Cu(n)BTA(m) clusters is protected by BTA-Cu(i)-BTA units.

Dynamic Diglyme-Mediated Self-Assembly of Gold Nanoclusters

We report the assembly of gold nanoclusters by the nonthiolate ligand diglyme into discrete and dynamic assemblies. To understand this surprising phenomenon, the assembly of Au20(SC2H4Ph)15-diglyme into Au20(SC2H4Ph)15-diglyme-Au20(SC2H4Ph)15 is explored in detail. The assembly is examined by high-angle annular dark field scanning transmission electron microscopy, size exclusion chromatography, mass spectrometry, IR spectroscopy, and calorimetry. We establish a dissociation constant for dimer to monomer conversion of 20.4 μM. Theoretical models validated by transient absorption spectroscopy predict a low-spin monomer and a high-spin dimer, with assembly enabled through weak diglyme oxygen-g…

Ag11(SG)7 : A New Cluster Identified by Mass Spectrometry and Optical Spectroscopy

We report a one-step and high yield synthesis of a red-luminescent silver cluster with the molecular formula, Ag11(SG)7 (SG: glutathionate) via reduction of silver ions by sodium borohydride in the presence of the tripeptide, glutathione (GSH). The as-prepared cluster shows prominent absorption features at 485 and 625 nm in its UV-vis absorption spectrum. Aging of the as-prepared cluster solution led to the disappearance of the 625 nm peak, followed by broadening of the 485 nm peak to give three maxima at ?487, 437, and 393 nm in its absorption spectrum. These peaks remain unchanged even after polyacrylamide gel electrophoresis (PAGE), where a single band was observed confirming high purity…

Real-time time-dependent density functional theory implementation of electronic circular dichroism applied to nanoscale metal–organic clusters

| openaire: EC/H2020/838996/EU//RealNanoPlasmon Electronic circular dichroism (ECD) is a powerful spectroscopy method for investigating chiral properties at the molecular level. ECD calculations with the commonly used linear-response time-dependent density functional theory (LR-TDDFT) framework can be prohibitively costly for large systems. To alleviate this problem, we present here an ECD implementation within the projector augmented-wave method in a real-time-propagation TDDFT framework in the open-source GPAW code. Our implementation supports both local atomic basis sets and real-space finite-difference representations of wave functions. We benchmark our implementation against an existin…

Search for low-mass resonances decaying into two jets and produced in association with a photon using pp collisions at s=13 TeV with the ATLAS detector

A search is performed for localised excesses in dijet mass distributions of low-dijet-mass events produced in association with a high transverse energy photon. The search uses up to 79.8 fb−1 of LHC proton–proton collisions collected by the ATLAS experiment at a centre-of-mass energy of 13 TeV during 2015–2017. Two variants are presented: one which makes no jet flavour requirements and one which requires both jets to be tagged as b-jets. The observed mass distributions are consistent with multi-jet processes in the Standard Model. The data are used to set upper limits on the production cross-section for a benchmark Z′ model and, separately, on generic Gaussian-shape contributions to the mas…

Fast and robust population transfer in two-level quantum systems with dephasing noise and/or systematic frequency errors

We design, by invariant-based inverse engineering, driving fields that invert the population of a two-level atom in a given time, robustly with respect to dephasing noise and/or systematic frequency shifts. Without imposing constraints, optimal protocols are insensitive to the perturbations but need an infinite energy. For a constrained value of the Rabi frequency, a flat $\pi$ pulse is the least sensitive protocol to phase noise but not to systematic frequency shifts, for which we describe and optimize a family of protocols.

A computer-based Pinyin intervention for disadvantaged children in China: Effects on Pinyin skills, phonological awareness, and character reading.

Pinyin is an alphabetic script that denotes pronunciations of Chinese characters. Studies have shown that Pinyin instruction enhances both phonological awareness (e.g., Shu et al., Developmental Science, 2008, 11, 171-181) and character reading (e.g., Lin et al., Psychological Science, 2010, 21, 1117-1122) in Chinese children. In the present study, we provided a 3-week Pinyin intervention with a computer-based Pinyin GraphoGame to disadvantaged migrant children with poor Pinyin skills. A total of 252 first graders who were children of migrant workers in a large Chinese city were assessed to identify poor Pinyin readers. Fifty-six 7-year-old children with poor Pinyin skills were selected and…

Study of the material of the ATLAS inner detector for Run 2 of the LHC

The ATLAS inner detector comprises three different sub-detectors: the pixel detector, the silicon strip tracker, and the transition-radiation drift-tube tracker. The Insertable B-Layer, a new innermost pixel layer, was installed during the shutdown period in 2014, together with modifications to the layout of the cables and support structures of the existing pixel detector. The material in the inner detector is studied with several methods, using a low-luminosity root s = 13 TeV pp collision sample corresponding to around 2.0 nb(-1) collected in 2015 with the ATLAS experiment at the LHC. In this paper, the material within the innermost barrel region is studied using reconstructed hadronic in…

Peripheral Blood and Cerebrospinal Fluid Cytokine Levels in Guillain Barré Syndrome: A Systematic Review and Meta-Analysis

Background: Guillain Barre Syndrome (GBS) is an autoimmune disorder caused by the immune-mediated damage of the peripheral nervous system. Increasing evidence suggests that inflammatory cytokines are important mediators for the onset and progression of GBS. A number of clinical studies have demonstrated elevated levels of T helper-1 (Th1-), Th2-, and Th17-related cytokines in patients with GBS; however, the results were inconsistent across studies. Methods: We performed a systematic review and a meta-analysis of studies comparing the levels of inflammatory cytokines in the cerebrospinal fluid and peripheral blood between patients with GBS and healthy individuals, using Comprehensive Meta-An…

Breaking adiabatic quantum control with deep learning

In the era of digital quantum computing, optimal digitized pulses are requisite for efficient quantum control. This goal is translated into dynamic programming, in which a deep reinforcement learning (DRL) agent is gifted. As a reference, shortcuts to adiabaticity (STA) provide analytical approaches to adiabatic speed up by pulse control. Here, we select single-component control of qubits, resembling the ubiquitous two-level Landau-Zener problem for gate operation. We aim at obtaining fast and robust digital pulses by combining STA and DRL algorithm. In particular, we find that DRL leads to robust digital quantum control with operation time bounded by quantum speed limits dictated by STA. I…

Fast shuttling of a trapped ion in the presence of noise

We theoretically investigate the motional excitation of a single ion caused by spring-constant and position fluctuations of a harmonic trap during trap shuttling processes. A detailed study of the sensitivity on noise for several transport protocols and noise spectra is provided. The effect of slow spring-constant drifts is also analyzed. Trap trajectories that minimize the excitation are designed combining invariant-based inverse engineering, perturbation theory, and optimal control.

CCDC 1020498: Experimental Crystal Structure Determination

Related Article: Huayan Yang , Yu Wang , Juanzhu Yan , Xi Chen , Xin Zhang , Hannu Häkkinen , and Nanfeng Zheng|2014|J.Am.Chem.Soc.|136|7197|doi:10.1021/ja501811j

CCDC 1020499: Experimental Crystal Structure Determination

Related Article: Huayan Yang , Yu Wang , Juanzhu Yan , Xi Chen , Xin Zhang , Hannu Häkkinen , and Nanfeng Zheng|2014|J.Am.Chem.Soc.|136|7197|doi:10.1021/ja501811j

CCDC 1496141: Experimental Crystal Structure Determination

Related Article: Huayan Yang, Yu Wang, Xi Chen, Xiaojing Zhao, Lin Gu, Huaqi Huang, Juanzhu Yan, Chaofa Xu, Gang Li, Junchao Wu, Alison J. Edwards, Birger Dittrich, Zichao Tang, Dongdong Wang, Lauri Lehtovaara, Hannu Häkkinen, Nanfeng Zheng|2016|Nat.Commun.|7|12809|doi:10.1038/ncomms12809

CCDC 1020496: Experimental Crystal Structure Determination

Related Article: Huayan Yang , Yu Wang , Juanzhu Yan , Xi Chen , Xin Zhang , Hannu Häkkinen , and Nanfeng Zheng|2014|J.Am.Chem.Soc.|136|7197|doi:10.1021/ja501811j

CCDC 1020497: Experimental Crystal Structure Determination

Related Article: Huayan Yang , Yu Wang , Juanzhu Yan , Xi Chen , Xin Zhang , Hannu Häkkinen , and Nanfeng Zheng|2014|J.Am.Chem.Soc.|136|7197|doi:10.1021/ja501811j

CCDC 1496142: Experimental Crystal Structure Determination

Related Article: Huayan Yang, Yu Wang, Xi Chen, Xiaojing Zhao, Lin Gu, Huaqi Huang, Juanzhu Yan, Chaofa Xu, Gang Li, Junchao Wu, Alison J. Edwards, Birger Dittrich, Zichao Tang, Dongdong Wang, Lauri Lehtovaara, Hannu Häkkinen, Nanfeng Zheng|2016|Nat.Commun.|7|12809|doi:10.1038/ncomms12809

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