A remarkable rearrangement during reaction between triazolopyridinium ylides and dimethyl acetylenedicarboxylate

6533b86ffe1ef96bd12cd127

RESEARCH PRODUCT

A remarkable rearrangement during reaction between triazolopyridinium ylides and dimethyl acetylenedicarboxylate

Belén Abarca Michael B. Hursthouse M. R. Metni D. J. Ando Rafael Ballesteros Gurnos Jones

subject

Dimethyl acetylenedicarboxylate chemistry.chemical_classification Chemistry Organic Chemistry Biochemistry Medicinal chemistry Toluene Cycloaddition chemistry.chemical_compound Ylide Drug Discovery Molecule Organic chemistry Solvent effects

description

Abstract The ylides from 2-acylmethyltriazolopyridinium salts ( 1 ) react with dimethyl acetylenedicarboxylate in toluene solution to give the 7-pyrroleninylpyrazolo[1,5-a]pyridines ( 5 ).

year	journal	country	edition	language
1991-09-01	Tetrahedron Letters

https://doi.org/10.1016/s0040-4039(00)93512-3

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