Direct C-H metalation with chromium(ii) and iron(ii): transition- metal host/benzenediide guest magnetic inverse-crown complexes

6533b870fe1ef96bd12d05ef

RESEARCH PRODUCT

Direct C-H metalation with chromium(ii) and iron(ii): transition- metal host/benzenediide guest magnetic inverse-crown complexes

Pablo García-álvarez Pablo Alborés Jan Klett Alan R. Kennedy Luca M. Carrella Luca Russo Robert E. Mulvey William Clegg Eva Rentschler

subject

alkali metals Metalation chemistry.chemical_element Mineralogy ALKALI METALS metalation Catalysis Queen (playing card)Chromium chemistry.chemical_compound iron Transition metal CHROMIUM inverse crown compounds Benzene IRON Otras Ciencias Químicas Ciencias Químicas General Chemistry Alkali metal Communications Crystallography chemistry chromium INVERSE CROWN COMPOUNDS CIENCIAS NATURALES Y EXACTAS

description

Check M(etal)ate: The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (usually the weaker piece) to make a direct deadly hit on the king (benzene) in this game of elemental chess. Fil: Alborés, Pablo. Johannes Gutenberg Universitat Mainz; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Carrella, Luca M.. Johannes Gutenberg Universitat Mainz; Alemania Fil: Clegg, William. University of Newcastle; Reino Unido Fil: García Álvarez, Pablo. University of Strathclyde; Reino Unido Fil: Kennedy, Alan R.. University of Strathclyde; Reino Unido Fil: Klett, Jan. University of Strathclyde; Reino Unido Fil: Mulvey, Robert E.. University of Strathclyde; Reino Unido Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania Fil: Russo, Luca. University of Newcastle; Reino Unido

year	journal	country	edition	language
2009-04-01

10.1002/anie.200805566 https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200805566

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